Geometric and electronic structures of methylene sulfurtetrafluoride, CH 2 SF 4, thionyl tetrafluoride, O SF 4, and sulfurtetrafluoride, SF 4: an ab initio studystructure (organic substancesFully optimized geometric structures for SF 4, O SF 4, and CH 2 SF 4 have been calculated by the ab ...
Sulfur reacts with fluorine to give the highly reactive sulfur tetrafluoride and the highly inert sulfur hexafluoride.[43] Whereas fluorine gives S(IV) and S(VI) compounds, chlorine gives S(II) and S(I) derivatives. Thus, sulfur dichloride, disulfur dichloride, and higher chlorosulfanes arise...
Although it can be prepared from Cobalt(III) Fluoride and Sulfur Tetrafluoride (utilizing Bromine), for a large-scale industrial production SF6 is synthesized from elemental Sulfur and Fluorine, respectively. Co-created Sulfur Fluorides (such as S2F10) during the synthesis are filtered out afterwards...
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Abstract References (36) Cited by (38) Journal of Molecular Structure Volume 56, 1979, Pages 107-116Geometric and electronic structures of methylene sulfurtetrafluoride, CH2 SF4, thionyl tetrafluoride, O SF4, and sulfurtetrafluoride, SF4: an ab initio studyAuthor links open overlay panelHeinz...