The subcomponent self-assembly of polymer chains based on the dynamic/geometrical coordination diversity of first row transition metal ions is reported. A well-defined NH2-functional hydrophilic block copolymer, Ni(ii), Cu(ii) and Zn(ii) and a salicylaldehyde derivative are selected as sub...
R. (2010), ChemInform Abstract: Subcomponent Self-Assembly as a Route to New Structures and Materials. ChemInform, 41: no. doi: 10.1002/chin.201021223 Author Information Dep. Chem., Univ. Cambridge, Cambridge CB2 1EW, UK Publication History Issue published online: 29 APR 2010 Article first ...
Subcomponent self-assembly allows for the construction of complex architectures from simple building blocks via the simultaneous, reversible formation of covalent and coordinative bonds. Complex structures may be rapidly built by taking advantage of the different and complementary selectivities of covalent and...
Hutin, M.; Schultz, D.; Nitschke, J. R. "From Simplicity To Complexity Via Subcomponent Self-Assembly," Chimia, 2008, 62, 198-203.M. Hutin, D. Schultz and J. R. Nitschke, from simplicity to complexity via subcomponent self-assembly, Chimia, 62 (2008) 198...
Inhibition of the activation of Hageman factor (factor XII) by complement subcomponent C1q. Construction, Substitution, and Sorting of Metallo-organic Structures via Subcomponent Self-Assembly Modulation of FcR function by complement: subcomponent C1q enhances the phagocytosis of IgG-opsonized targets by ...
Rational control over the self-assembly of discrete, nanometre-scale, hollow coordination cages composed of simple components remains challenging as a result of the entropic costs associated with binding many subunits together, difficulties in the error-correction processes associated with assembly and ...
Here, we present a new mononuclear Fe(II) complex with formula [FeL 2 ](BF 4 ) 2 (L=( E )-2-((pyridin-2-ylmethylene)amino)-1 H -benzo[ de ]isoquinoline-1,3(2 H )-dione) ( 1 ) for potential NH 3 sensing applications. Complex 1 was synthesized via subcomponent self-assembly...
Insights into the subcomponent self-assembly of extended PBI ligands help to refine design rules for constructing large photofunctional metallosupramolecular hosts.Frischmann, Peter D.Kunz, ValentinStepanenko, VladimirWuerthner, FrankChemistry: A European journal...
A variety of different three-dimensional metal鈥搊rganic container molecules have recently been prepared using subcomponent self-assembly, which relies upon metal template effects to generate complex structures from simple molecular precursors and metal salts. Many of these structures have well defined ...
We describe herein the extension of this "subcomponent self-assembly" concept to the generation of structures based upon the iminoboronate ester motif. Equimolar amounts of diol, amine, and 2-formylphenylboronic acid reacted by reversible B-O and C=N bond formation to generate iminoboronate ...