The reaction of allyl alcohol and PdC1 at about 50 掳C to form a greenish-yellow crystalline complex was first described by Smidt & Hafner (1959) and by Moiseev et al. (1959). D e h m & Chien (1960) investigated solutions of the allylpalladium chloride complex in deuterochloroform by...
The only structural analysis of an allyl complex so far reported is that of the dimeric π-allyl palladium chloride3, the reaction of this complex with silver acetate yielding π-allyl palladium acetate4. A three-dimensional X-ray analysis of the structure of this molecule has now been ...
Ab initio molecular orbital calculations at the STO-3G and 3-21G levels were used to clarify the mechanism of mutagenic action of various substituted allyl chlorides. Computed molecular properties were compared with experimental mutagenic potentials of these allylic compounds. In agreement with experiment...
Calculations on the π-allyl-Pd(II) chloride dimer ( 1 ) have been performed at HF and DFT levels with different basis sets. Symmetry restricted minimizations were performed and the results were compared with the experimental values. In addition, theoretical studies on the topology of the charge...
select article Synthesis and characterization of a self-healing Epichlorohydrin-co-Ethylene Oxide-co-Allyl Glycidyl ether–based polymer by modification using the stable Nitroxide Radical 2,2,6,6-Tetramethylpiperidine 1-oxyl Research articleAbstract only Synthesis and characterization of a self-...
5-allyl-2-hydroxy-3-methoxyazobenzene was preperad by the reaction of 4-allyl-2-methoxyfenol and benzenediazoniumchloride and crystallized from dimethylsulphoxide to yield crystals suitable for analysis. The molecular structure was identified by UV-VIS, IR, 1H-NMR, 13C-NMR and elemental ...
Queuosine (Q) is a structurally complex, non‐canonical RNA nucleoside. It is present in many eukaryotic and bacterial species, where it is part of the anticodon loop of certain tRNAs. In higher vertebrates, including humans, two further modified queuosi
Structure-activity relationship in halogen and alkyl substituted allyl and allylic compounds: Correlation of alkylating and mutagenic properties In a series of allylic chloroolefins and their non-allylic isomers the significance of the allylic structure and the influence of methyl and chlorine substituents...
Interactive 3D animations of cis and trans decalins showing conformational changes for students on University chemistry courses.
select article Synthesis, X-ray structure, vibrational spectroscopy, DFT, biological evaluation and molecular docking studies of (E)-N’-(4-(dimethylamino)benzylidene)-5-methyl-1H-pyrazole-3-carbohydrazide Research articleAbstract only Synthesis, X-ray structure, vibrational spectroscopy, DFT, biological...