The redshift in the low-energy emissions for compounds 1 and 3 are consistent with the presence of some Ag contribution to the HOMO so that a triplet metal to ligand charge transfer 3[MLCT] excited state assignment is tempting. However, the small magnitude of this redshift for compound 2 ...
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The charge transfer in physical adsorption (<0.025 e) was quite low compared with that in chemical adsorption (0.294~1.087 e). The adsorption of CO2 on the pristine graphene was quite weak, with a large adsorp- tion distance (3.398 Å), and the partial density of state remained almost ...
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