Dietmar SeyferthOrganometallicsSeyferth D (2006) Alkyl and aryl derivatives of the alkali metals: useful synthetic reagents as strong bases and potent nucleophiles. 1. Conversion of organic halides to organoalkali-metal compounds. Organometallics 25:2-24...
Electrolytes are compounds that are capable of conducting electricity when in aqueous or molten state. This is possible due to the dissociated ions - positively and negatively charged- dispersed in the solution. Strong electrolytes such as soluble ionic compounds, and strong ...
As P‐bases, the title compounds display calculated proton affinities between 265.8 (NR2 = NMe2) and 274.7 kcal· mol–1 [NR2 = N(CH2)4] and pK BH values between 26.4 (NR2 = NMe2) and 31.5 [NR2 = N(CH2)4] on the acetonitrile scale. As P‐nucleophiles, they are key ...
These easily accessible mixed valent compounds display a surprisingly high proton affinity and basicity in the same range as the corresponding Schwesinger diphosphazene (Me2N)3P=N–P=NEt(NMe2)2 (Et-P2) and Verkade's proazaphosphatrane superbases. Within the central [PIII–N=PV] scaffold, ...