Quantitative conversion measurements show that the reactivity rises rapidly as the length of the paraffinic side group increases, reaches a maximum value for the bis(capric acid) ester and then falls steadily, to almost no reaction, for the highest member of the series. Optical and Raman ...
processes11,12. However, these observations are always challenging to make underoperandoconditions, in particular at elevated temperatures13and realistic (1 atm and higher) pressures. In addition to shape-dependent catalytic activity, lattice strain14has a considerable influence on the reactivity of met...
Metallaboranes of the Early Transition Metals: Direct Synthesis and Characterization of [{(η 5 -C 5 Me 5 )Ta} 2 B n H m ] ( n =4, m =10; n =5, m =11), [{(... Reaction of [Cp*TaCl4] (Cp*=路5-C5Me5) with a sixfold excess of LiBH4thf followed by BH3thf in ...
Hence, several studies have attempted to find solutions to avoid, or at least to limit the dendritic growth phenomenon. Due to the high reactivity of lithium, a passivation layer is formed on the lithium anode. This passivation layer acts as a solid “ion-conductive” electrolyte (SE) film,...
HSAB principle: applications of its global and local forms in organic chemistry. Int. J. Quantum Chem. 80, 227–235 (2000). Article CAS Google Scholar Crawford, P. & Hu, P. Reactivity of the 4d transition metals toward N hydrogenation and NH dissociation: a DFT-based HSAB analysis. J...
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry 被引量: 0发表: 2016年 Synthesis, Crystal Structure, and Cytotoxic Property of Zinc (II) Complex Derived From N,N '-bis(5-fluorosalicylidene)-1,2-diaminoethane The synthesis and crystal structure of a new monon...
The catalytic activity of metal clusters often shows an interesting cluster size selectivity, e.g., metals which are inert in bulk form can become extraord... YD Kim - 《International Journal of Mass Spectrometry》 被引量: 73发表: 2004年 Experimental and theoretical infrared spectra of Co2CO ...
{Delta}x{sub spec} = x{sub spec}{sup A} - x{sub spec}{sup B}, the energy difference of an average electron in atom A and in atom B, is able to systematize properties of the vast array of known materials: ionic solids, covalent molecules, metals, minerals, inorganic and organic ...
Moreover, the reactivity of the electrolyte with the cathode material can also lead to the dissolution of transition metals from the cathode, which further deteriorates the battery performance by contaminating the electrolyte and the anode [17]. The degradation of the electrolyte and electrodes due ...
The kinetic theory of gases can also be applied to the free-electron gas to describe the transport properties of metals, obtaining the result that the ratio of the thermal and electrical conductivities is a universal constant times the temperature (the Wiedemann–Franz law). ...