Excitation (410 nm) of the bimetallic [(bpy)(2)Ru(CN)(mu-CN)Rh(NH(3))(4)Br](2+) produces the MLCT state localized on the (bpy)(2)Ru(CN)(2) ligand. Photoinduced cleavage of the bimetallic occurs in the presence of [H(+)], and the dependence yields a K(a) equivalent to th...
Comparison of the characteristic bond lengths based on the X-ray structure of 4 with previously reported NH-forms of other Schiff bases revealed that the structure of 4 was a hybrid of two canonical structures, namely, zwitterion and quinoid, contributing to the resonance. It was also found ...
the positive influences of reinforcement ratio, column cross-sectional dimensions, axial load level, material strain rate effects, and impact velocity and weight of vehicle were found on the peak value of impact force. However,
The use of externally bonded fiber reinforced polymer (FRP) sheets, strips or steel plates is a modern and convenient way for strengthening of reinforced concrete (RC) beams. Several researches have been carried out on reinforced concrete beams with web openings that strengthened using fiber reinforc...
pro- and anti-inflammatory roles in pathologic conditions, demarcation from other forms of cell death, or the origin of the DNA that forms the NET scaffold. Here, we present prevailing concepts and state of the science in NET-related research and elaborate on open questions and areas of ...
Prudence, indeed, will dictate that governmentslong established should not be changed for light and transient causes; andaccordingly all experience hath shown that mankind are more disposed to suffer,while evils are sufferable, than to right themselves by abolishing the formsto which they are accustom...
Circular dichroism (CD) spectral examinations at various host/guest ratios revealed that 2-anthracenecarboxylic acid (AC) forms not only 1:1 but also novel... Y Kawanami,SY Katsumata,JI Mizoguchi,... - 《Organic Letters》 被引量: 45发表: 2012年 Solid-phase synthesis of peptides containing ...
Ligand-receptor systems, covalent modification cycles, and transcriptional networks are basic units of signaling systems and their steady-state properties are well understood. However, the behavior of such systems before steady-state is poorly characteri
Both graphene and GO could be used as sensors and biosensors, but the functionalisation of GO, because of its oxygen groups, is much easier than the reduced form. However, both forms could be used as a base material for developing a sensor. Graphene and GO have been studied for sensory ...
Only a minor proportion (estimated 1–2%) of liraglutide circulates in a free (non-albumin-bound) form, ready to diffuse into tissues and bind receptors. The albumin-bound bulk forms a reservoir promoting prolonged action. Overall, the elimination half-life is approximately 13 h, making it a...