Explore state functions. Learn the definition of state function and understand how it differs from path functions. Discover examples of state...
The nanopore array serves two functions: 1) to spatially immobilize the probe molecules in given locations and 2) to support objects such as live cells on solid surfaces.EXAMPLESExample #1Unfolded DNA Translocation Governed by Interactions with Solid State Nanopores...
substitution (for example,deuteriumfor hydrogen). It is often found, however, that a unique structure cannot be found consistent with all the moments of inertia. The reason is that the different vibrational wave functions in the isotopically substituted molecules yield slightly different average ...
In some instances, it functions as the main energy donor state, selected examples being [Ln(L11)3(tpy)] (Ln = Nd, Er),90 L12[Eu(tta)4],97 Na[Yb(L13x)4],34 or [Yb(hfa)3(L14)2];96 see Scheme 3 for ligand structures. The ILCT states are usually located at low energy, so...
We used the triple-ζ basis set with two polarization functions (TZ2P) and quadruple-ζ basis set with four polarization functions (QZ4P). The gradient corrected GGA-PBE78, meta-GGA TPSS79, and hybrid B3LYP* and B3LYP80 functionals were employed. Solvent effects of THF were simulated within...
All EEG analyses were implemented by custom-made routines developed in Matlab R2013a (The MathWorks, Inc., Natick, Massachusetts, United States) using EEGLab toolbox functions (v. 13.0.1)69. EEG data processing Resting state EEG data were band-pass filtered (using a Hamming windowed sync FIR...
These functions are linked together in feedback loops involving electrical or chemical sensors, termed “homeostats”. The feedback loop may malfunction as a result of disease-causing mutations in any of the components. Given the effects of these disorders on cognition, it is likely no accident ...
ATTR amyloidosis is caused by the presence of an abnormal plasma pre-albumin protein that normally functions to transport thyroxine and retinol-binding protein and was subsequently termed transthyretin. Since the discovery of this form of amyloid many different clinical manifestations resulting from the ...
As the two-configurational wavefunctions discussed here are of the “complete active space” (CAS) type (i.e., all possible configurations of two electrons in the two “active” orbitals are considered, basically a full-CI within the active space), they are invariant to arbitrary orbital ...
In subject area: Chemistry In the formalism of “transition state theory” the transition state of an elementary reaction is that set of states (each characterized by its own geometry and energy) such that an assembly of atoms, when randomly placed there, would have an equal probability of for...