V. R. Schleyer, "Evidence for d orbital aromaticity in square planar coinage metal clusters," Journal of the American Chemical Society, vol. 127, no. 15, pp. 5701- 5705, 2005.Wannere C.S,Corminboeuf C,Wang Z.X,Wodrich M.D.,King R.B.,Schleyer P.R. Evidence for d orbital ...
The layered square-planar nickelates, Ndn+1NinO2n+2, are an appealing system to tune the electronic properties of square-planar nickelates via dimensionality; indeed, superconductivity was recently observed in Nd6Ni5O12thin films. Here, we investigate the role of epitaxial strain in the competin...
The layered square-planar nickelates, Ndn+1NinO2n+2, are an appealing system to tune the electronic properties of square-planar nickelates via dimensionality; indeed, superconductivity was recently observed in Nd6Ni5O12thin films. Here, we investigate the role of epitaxial strain in the competin...
Herein, we show that the novel compound BaCoAs2O5, with lone-pair As3 ions, is built from rare square-planar Co2 O4 involved in direct bonding between As3 E and Co2 d z2 orbitals (Co–As=2.51 ). By means of DFT and Hückel calculations, we show that this σ-typ...
Two‐Orbital Three‐Electron Stabilizing Interaction for Direct Co2+As3+ Bonds involving Square‐Planar CoO4 in BaCoAs2O5Two‐Orbital Three‐Electron Stabilizing Interaction for Direct Co2+As3+ Bonds involving Square‐Planar CoO4 in BaCoAs2O5doi:10.1002/ange.201311183Arsenite...
Evidence for d Orbital Aromaticity in Square Planar Coinage Metal Clusters. (p )doi:10.1002/chin.200525001theory, structuretransition metalslithium, LiFor Abstract see ChemInform Abstract in Full Text.John Wiley & Sons, Ltd.ChemInform
A Molecular Orbital Study of Trans Influence and Kinetic Trans Effect in Square-Planar Platinum(II) ComplexesZumdahl, Steven SDrago, Russell S
Phelan, D.Zheng, HongPardo, V.Norman, M. R.Mitchell, J. F.Nature PhysicsNature PhysicsJ. Zhang, A. S. Botana, J. W. Freeland, D. Phelan, H. Zheng, V. Pardo, M. R. Norman, J. F. Mitchell, Large orbital polarization in a metallic square-planar nickelate. Nature Phys. 13, ...
Ab initio (RHF/3-21G*) calculations on Sn[(SePR2)(2)N](2) (R=H) suggest that tin coordinated by four selenium atoms does not have a strong preference either for square planar nor for pyramidal geometry. According to the semiempirical PM3 calculations performed at the experimental geometries...
doi:10.1002/anie.201311183Rénald DavidHouria KabbourAlain PautratNadia TouatiMyung-Hwan WhangboOlivier MentréAngewandte Chemie International Edition