With respect to theoretical studies, Anderson first proposed that the triangular Heisenberg antiferromagnet (THAF) has a resonating valence bond GS, which is a type of spin liquid2,3. However, recent numerical studies have consistently indicated a long-range Néel GS for spin-1/2 THAF. The ...
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29 October 2018 Published: xx xx xxxx Marco Finazzi , Federico Bottegoni, Carlo Zucchetti , Giovanni Isella & Franco Ciccacci Spin transport phenomena have been shown to be highly enhanced when the temperature approaches the Curie point of the material sustaining a ...
K is plot- ted together with the macroscopic susceptibility, in Fig. 2. The scaling of the Knight shift is good down to ~15 K. Below 15 K, the K shows qualitatively the same T-dependence with χ, but the ie.er.r,oKr =ba Arshyop ·f χK, become large at low ...
ZnO films have thermal diffusivity in the range (4.35–5.03) × 10−2 cm2/s and electrical resistivity varying from 10−4 to 1012 Ω.cm6. The as-grown ZnO exhibits n-type conductivity due incorporated hydrogen dtourniantgivcerdysetfaelcgtsrosuwcthh7a.sZZnnOinitseo...
As a consequence of the diverging reaction coordinates in [FeL]2+ and in the tren-derived complex [Fe(tren)py3]2+, their thermal barriers differ massively, although the spin crossover energies are close to identical. As is shown by time-resolved transient spectroscopy and dynamic 1H-NMR ...
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Currently, special attention is given to SCO compounds exhibiting pronounced cooperative behavior. Here, the mononuclear system [Fe(bpp)2]2+ (bpp = 2,6-di{pyrazol-1-yl}pyridine) [1–4], as well as the triazole-based mono-/bi-nuclear [Fe2(PMAT)2]4+ system [5–8], are among the ...
Naturally-occurring examples of such systems include the metal complexes that play important roles in various biological functions, such as the transportation of oxygen, gene activation, and the catalytic reactions of enzymes [2,3]. The field of biomimetic chemistry aims both to understand and to ...