Moreover, the Philadelphia-based researchers found that addition of HOCH2CCl3 (up to 600 equiv) to CeCl62– in the absence of light or under irradiation under the conditions of the C–H functionalization induced no changes in the UV-vis spectrum from CeCl62–, indicating that [CeCl5(OCH2...
Strategies that enable intermolecular site-selective C–H bond functionalisation of organic molecules provide one of the cornerstones of modern chemical synthesis. In chloroalkane synthesis, such methods for intermolecular site-selective aliphatic C–H b
The spectra reveal that all six complexes share structural similarities, each featuring two N=CH units and two OCH₃ groups. For instance, in the 1H NMR spectrum of complex 1, the protons on the N=CH units and OCH₃ groups appear at 8.77 and 3.92 ppm, respectively, suggesting a ...