Solvation effects in the second organic phase in lanthanide extraction by benzyldialkylamines have been investigated by means of chemical analysis of the second organic phase, liquid chromatography, osmometric data and logarithmic analysis.doi:10.1007/BF02036496V. Jedináková...
Solvents and Solvent Effects in Organic Chemistry (Wiley, 2011). Marcus, Y. Ions in Solution and Their Solvation (John Wiley & Sons, 2015). Toennies, J. P. & Vilesov, A. F. Superfluid helium droplets: a uniquely cold nanomatrix for molecules and molecular complexes. Angew. Chem. Int....
In studies performed in order to better understand these solvent effects, considerable research has been carried out on the physical organic chemistry of mixed solvents [4], [5], [6], [7], [8], [9], [10], [11], [12], [13], [14], [15], [16], [17], [18], [19], [20...
- 《Journal of Computational Chemistry》 被引量: 305发表: 1996年 Hydrogen Bond versus Polar Effects:? An Ab Initio Analysis on n →π* Absorption Spectra and N Nuclear Shieldings of Diazines in Solution The complex nature of the effect of H-bonding solvents on electronic and magnetic ...
(Chemistry) the process in which there is some chemical association between the molecules of a solute and those of the solvent. An example is an aqueous solution of copper sulphate which contains complex ions of the type [Cu(H2O)4]2+ ...
950-954 Department of Physical Chemistry, Institute of Organic Materials Science, Technical University of Radom ( Poland) The Solvation Effects of Aliphatic Amines in Aromatic Solvents By M. W. Sulek1 With 1 Figure and 1 Table (Received 30th May 1985; in rev. version 7th November 1985) ...
Conformational properties of a model alanyl dipeptide and of alanine-derived oligopeptides: Effects of solvation in water and in organic solvents - A combi... Salahub, Conformational properties of a model alanyl dipeptide and of alanine-derived oligopeptides: Effects of solvation in water and in orga...
It is important to note that while the standard notion for solvation free energy is defined for the dilute limit, in this work, we consider practically more relevant finite concentrations where the solvation free energy includes the concentration effects. In essence, our measured concentration-...
The previously developed general method (IDME), which includes calculation of electrostatic and solvation effects on conformational equilibria, has been ex... Ljiljana,Došen-Mićović,Shusen,... - 《Journal of Physical Organic Chemistry》 被引量: 168发表: 1991年 Use of Locally Enhanced Sampli...
The solvated yttrium(III) ion has been shown by XAFS and large angle X-ray scattering to coordinate eight solvent molecules in both DMSO and DMF, but only six inN,N′-dimethylpropyleneurea due tosteric effects. XRD results show the ionic radii of YIIIto increase about 0.12Å from six to...