Compound 3 was completely characterised and the molecular structure determined by single-crystal X-ray diffraction. Complex 3 crystallises in the monoclinic system, space group C2/c, with a = 26.9527(10), b = 10.9558(7), c = 19.2104(10) , β = 127.268(2), V = 4514.3(4) 3 and Z ...
The temperature of the peak of the lambda shape (maximum thermal conductivity) is just above the melting point Tmelt≈ 303.8 K (30.6°C) for pure 1-ethyl-3-methylimidazolium methanesulfonate [2], and below the quoted melting point of ST35 by BASF 308 K (35 °C). However, upon ...
Dicationic units of 3 which present an unusual paddle wheel-like shape constitute appropriate organometallic building blocks for the construction of a supramolecular solid-state architecture. The analysis of the packing of the molecules of 3 in the crystal revealed an unprecedented 2-dimensional ne...
Recently we found a new non-solvate compound [Fe(qsal)2](CH3OSO3) (1) as very large rhombic platelets with a flat crystal surface (Figure 1). As we tried to prepare the related compounds with similar size and shape anions, we obtained relatively large crystals of the known non-solvate...