In this review, we feature key recent discoveries and advances across the whole range of σ-hole interactions for anion recognition, from the familiar halogen bonding to the almost unknown pnictogen and tetrel
Sigma-hole造成的次级键作用在p区结构化学中有十分重要的作用。立足于此类相互作用的催化等应用也因此应运而生。此文简单地介绍一下此类相互作用。 Ref: ①Lim and Beer, Sigma-Hole Interactions in Anion Recognition, Chem (2018),doi.org/10.1016/j.chemp ②Han, Zhumin et al. “Imaging the halogen bon...
However, contemporary research in the design of anion transporters has exploited exotic sigma-hole-based noncovalent interactions such as XB, ChB, and PnB to mediate anion recognition. These interactions arise from the interaction of a Lewis base (i.e., anions) with a Lewis-acidic main-group ...
LONG-RANGE INTERACTIONS .2. A MODEL SYSTEM FORSIGMA-INTERACTION BETWEEN ALLYLIC ANION AND OLEFINdoi:10.1039/j29690000868BROWN, JJOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC
Sigma-Hole Interactions in Anion Recognition. Chem-Us 2018, 4, 731–783. [CrossRef] 59. Liu, Y.-Z.; Yuan, K.; Liu, L.; Yuan, Z.; Zhu, Y.-C. Anion Recognition Based on a Combination of Double-Dentate Hydrogen Bond and Double-Side Anion−π Noncovalent Interactions. J. Phys. ...