Thorfinnur GunnlaugssonSchool of Chemistry and Trinity Biomedical Sciences Institute (TBSI)Angewandte ChemiePandurangan, K. et al. Unexpected self-sorting self-assembly formation of a [4:4] sulfate:ligand cage from a preorganized tripodal urea ligand. Angew....
Supramolecular self-assembly of μm-to-mm sized components is essential to construct complex supramolecular systems. However, the selective assembly to form designated structures at this length scale is challenging because the short-ranged molecular recognition could hardly direct the assembly of macroscopi...
Self-assembly process of the cage(s). As the self-assembly processes of the Pd214cage(s) from1Sand from a racemic mixture of1are the same except diastereomers for the intermediates and the cages, the chirality of1(1Sor1R) is not shown in this figure. The dashed arrows indicate minor p...
Dynamic covalent self-assembly of small and rigid precursors into cage-type architectures can serve as a powerful strategy for the formation of molecular porous units. In order to enhance the functionality of suchlike nanostructures, formation of complex multicomponent assemblies with high spatial precisi...
We investigate the self-assembly of polydisperse polyelectrolyte−amphiphile complexes (PACs) on the basal plane of highly ordered pyrolytic graphite (HOPG) at submonolayer coverage. The PACs assemble as straight rods that organize into raftlike structures on the surface. We find length self-...
self-assemblyself-sortingsupramolecular polymersA unique narcissistic self‐sorting system is composed of two structurally similar mono‐ and bisnaphthalene‐based supramolecular monomers. Upon cooling the pure mono‐ and bisnaphthalene monomers in a nonpolar solvent, toroidal and helicoidally elongated ...
We further show that the three palladium cages coexist in solution upon post-assembly mixing due to the very slow ligand exchange whereas treatment of binary mixtures of the corresponding ligands with Pd(II) leads to the formation of mixed cages comprising a statistical ligand distribution. In ...
A Simple and Highly Effective Ligand System for the Copper(I)‐Mediated Assembly of Rotaxanes a few minutes simply through mixing the components in solution at room temperature and they can be isolated through removal of the solvent or precipitation... CJ Campbell,DA Leigh,IJ Vitorica‐Yrezabal...
In an effort to model the behavior of multivalent receptors in biological systems, we have developed a biomimetic approach to the synthesis of modular, multivalent receptors in aqueous solution by molecular self-assembly. Our system is b... AR Urbach - American Chemical Society Southwest Regional ...
We have made particular emphasis on co-assembly processes in binary mixtures leading to supramolecular structures of remarkable complexity and the influence of different external variables such as solvent and concentration to direct recognition or discrimination processes between these species. The ...