Self-assembly process of the interlocked cage. The self-assembly of the Pd418 interlocked cage (IC) takes place through reaction steps (1)–(6): (1) formation of the Pd214Py* partial cage (PC) from PdPy*4(BF4)2 and the ditopic ligand 1 by ligand exchanges between Py* (3-chloropyrid...
A copolymer layer is then formed between each neighboring pair of guiding pattern portions and thereafter a directed self-assembly process is performed that causes phase separation of the various polymeric domains of the copolymer layer. Each guiding pattern portion is selectively removed, followed by ...
The unique kinetics in the nucleation process was confirmed as a thermal hysteresis in a cycle of assembly and disassembly processes. Under appropriate conditions within the hysteresis loop, addition of preassembled nanofiber seeds leads to seeded polymerization from the termini of the seeds in a ...
Chondroitin-based nanoplexes as peptide delivery systems--Investigations into the self-assembly process, solid-state and extended release characteristics. 来自 国家科技图书文献中心 喜欢 0 阅读量: 25 作者:A Umerska,KJ Paluch,MJ Santos-Martinez,C Medina,OI Corrigan,L Tajber ...
Binding of the ligand repeat unit to form a new layer is commonly a slow process, taking typically overnight to complete. This renders the process of multilayer preparation exceedingly slow and, in many cases, impractical. Here we describe a method for LbL synthesis of self-assembled ...
(1), let us consider a system of n precursor molecules of type X undergoing a self-assembly process on the surface. Suppose that we model the system trajectory as a discrete-time random walk on the island combination network, where this random walk evolves in such a way that the free ...
Self-assembly is a ubiquitous process in biology where it plays numerous important roles and underlies the formation of a wide variety of complex biological structures. Over the past two decades, materials scientists have aspired to exploit nature's assembly principles to create artificial materials, ...
(3) hybrid top–down/bottom–up systems that leverage traditional lithographic microfabrication alongside self-assembly processes6,7,8. These systems benefit from the robust sequence complimentarity and specificity of DNA. However, DNA nanostructures are dependent on high salt concentrations for structural...
(Pcomp)11,54. While the charge separation at the electrodes, together with the compensational polarization, creates a polarization field (Epol), thePinresults in the formation of a depolarization field (Edep) in the opposite direction. The dipole reversal process and the shape of the ...