The Scholl Reaction is a type of reaction in chemistry that allows for the direct formation of carbon-carbon bonds between aromatic rings. It is catalyzed by a combination of a Lewis acid and an oxidant, and it does not require specific functional groups. This reaction is advantageous because ...
TechValeriyaTechHellmannTechSarahTechBergerTechReinhardTechChemical communicationsGratz, S.; Beyer, D.; Tkachova, V.; Hellmann, S.; Berger, R.; Feng, X.; Borchardt, L. The mechanochemical scholl reaction--A solvent-free and versatile graphitization tool. Chem. Commun. 2018, 54, 5307-5310....
1.98 mmol) in dioxane (9.0mL) and stirred at room temperature for 3 h. The reaction mixturewasconcentrated in vacuo and the residual solid was suspended in water (20 mL).Careful adjustmentto pH 8 with 1 M aqueous HCl afforded a precipitate. Thewhi...
1.98 mmol) in dioxane (9.0mL) and stirred at room temperature for 3 h. The reaction mixturewasconcentrated in vacuo and the residual solid was suspended in water (20 mL).Careful adjustmentto pH 8 with 1 M aqueous HCl afforded a precipitate. Thewhite solid thus...
A 0.50 M LiOH solution (9.0 mL,4.5 mmol, 2.02 equiv.) was added dropwise to a solution of ester10(772 mg, 1.98 mmol) in dioxane (9.0mL) and stirred at room temperature for 3 h. The reaction mixturewasconcentrated in vacuo and the residual solid was suspended in water (20 mL).Carefu...
Nanographenes and graphene nanoribbons are promising materials with potential applications in organic and nano-electronics.1 During the bottom-up synthesis of these nanographenes the Scholl reaction2'3,a Lewis-acid catalysed oxidative cyclodehydrogenation is utilized to planarize precursor systems by forming...
The mechanochemical Scholl reaction as a versatile synthesis tool for the solvent-free generation of microporous polymersdoi:10.1039/D0RA05279EAnnika KrusenbaumSven GrtzSarah BimmermannStefanie HutschLars BorchardtThe Royal Society of Chemistry