原文(扫描或长按二维码,识别后直达原文页面): Azoarene activation for Schmidt-type reaction and mechanistic insights Fan-Tao Meng, Ya-Nan Wang, Xiao-Yan Qin, Shi-Jun Li, Jing Li, Wen-Juan Hao,* Shu-Jiang Tu, Yu Lan,* Bo Jiang*...
该项研究工作得到了国家自然科学基金及江苏师范大学的经费支持。 Azoarene activation for Schmidt-type reaction and mechanistic insights Fan-Tao Meng, Ya-Nan Wang, Xiao-Yan Qin, Shi-Jun Li, Jing Li, Wen-Juan Hao,* Shu-Jiang Tu, Yu Lan,* Bo Jiang* Nat. Commun.2022, 13 , 7393, DOI: 10.1...
Meng, FT., Wang, YN., Qin, XY. et al. Azoarene activation for Schmidt-type reaction and mechanistic insights. Nat Commun 13, 7393 (2022). DOI: 10.1038/s41467-022-35141-4 https://doi.org/10.1038/s41467-022-35141-4 催化技...
Reaction mechanismsThe Schmidt rearrangement, a reaction that enables C-C or C-H 蟽 bond cleavage and nitrogen insertion across an aldehyde or ketone substrate, is one of the most important and widely used synthetic tools for the installation of amides and nitriles. However, such a reaction ...
Fig. 2: Schmidt-type reaction for the synthesis of bicyclic 2-pyridinones. Reaction conditions:1(0.2 mmol),2(0.4 mmol), JohnPhosAu(MeCN)SbF6(1 mol%), DCE (2.0 ml), room temperature (rt), 6 h; the yield refers to isolated yield based on1; use of cyclopentyl acetate1...
this represents the Kolbe-Schmidt reaction. We know in that reaction, we're going to get the addition of a carboxylic acid that is ortho to the hydroxyl group here. So we're going to put a carboxylic acid here. So that's what we have initially with steps 1 and 2. Now for steps 3...
1.β-nitrostyrene was synthesized by ultrasonic Henry reaction and the accessory ingredient of alcohol Claisen-Schmidt reaction,using benzaldehyde and nitromethane as raw materials.分别研究了在超声波辅助Henry反应和甲醇助剂存在Claisen-Schmidt反应的条件下由苯甲醛、硝基甲烷合成β-硝基苯乙烯的反应条件,发现Clais...
17.Knoevenagel-type Condensation Reactions Promoted by Organocatalyst;有机小分子促进的Knoevenagel类缩合反应 18.A Study of the Benzoin Condensation Reaction Using the PTC UNDER Microwave Heating;微波加热相转移催化安息香缩合反应 相关短句/例句 Claisen-Schmidt condensationClaisen-Schmidt缩合 ...
Modified fluorapatite as highly efficient catalyst for the synthesis of chalcones via Claisen-Schmidt condensation reaction [J]. Adsorption, 2016, 80: 100. [9] SADVILKAR V G, SAMANT S D, GAIKAR V G. Claisen-Schmidt reaction in a hydrotropic medium [J]. J Chem Technol Biotechnol, 1995, ...
Schmidt Reaction and Its Applications in Natural Product Synthesis Schmidt反应及其在全合成中的应用 9. A block Gram-Schmidt algorithm with its application 分块Gram-Schmidt正交化算法及其应用 10. Some Discussion on Schmidt s orthogonalization by Matrix Method; 关于利用矩阵方法简化Schmidt正交化过程的研...