Schenck rearrangementSmith rearrangementIt is 50 years since Schenck's discovery of the ubiquitous rearrangement of allylic hydroperoxides, and its unique homolytic mechanism has now been clarified by a combination of experimental and computational methods. The recognised examples of the reaction are ...
Singlet-oxygen ene reaction with 3β-substituted stigmastanes. An alternative pathway for the classical Schenck rearrangement. María A Ponce,Javier A Ramirez,Lydia R Galagovsky,Eduardo G Gros,Rosa Erra-Balsells. Journal of the Chemical Society, Perkin Transactions 2 . 2000...