The Sabatier principle states that optimal catalysis occurs when interactions between catalyst and substrate are of intermediary strength. Although qualitative in nature, this concept has proven extremely useful within (nonbiochemical) heterogeneous catalysis. In the current work, we show that the ...
Summary This chapter contains sections titled: Introduction Sabatier's Principle in Heterogeneous Catalysis Exceptions to Sabatier's Principle Sabatier's Principle in Homogeneous Catalysis Conclusions. Sabatier's Principle Describes Two Independent Catalytic Domains: Energy- and Time-Dependent Catalysis ...
The Sabatier principle is a qualitative concept in chemical catalysis named after the French chemist Paul Sabatier. It states that the interactions between the catalyst and the substrate should be "just right"; that is, neither too strong nor too weak. If the interaction is too weak, the ...
The Sabatier principle is a qualitative concept in chemical catalysis named after the French chemist Paul Sabatier. It states that the interactions between the catalyst and the substrate should be "just right"; that is, neither too strong nor too weak. If the interaction is too weak, the ...
Sabatier principle of metal-support interaction for design of ultrastable metal nanocatalysts Sulei Hu and Wei-Xue Li* Hefei National Laboratory for Physical Sciences at the Microscale, School of Chemistry and Materials Science, Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of ...
Sabatier principleScaling relationDescriptorWe discuss three concepts that have made it possible to develop a quantitative understanding of trends in transition-metal catalysis: scaling relations, activity maps, and the d-band model. Scaling relations are correlations between surface bond energies of ...
K. From the Sabatier Principle to a Predictive Theory of Transition-Metal Heterogeneous Catalysis. J. Catal. 2015, 328, 36-42.A.J. Medford, A. Vojvodic, J.S. Hummelshoj, J. Voss, F. Abild-Pedersen, F. Studt, et al., From the Sabatier principle to a predictive theory of transition...
多相催化反应过程伴随着反应分子与催化剂表面之间的相互作用.这种相互作用强度与催化剂的反应性能密切相关.根据萨巴蒂尔原理(Sabatier principle),性能最优的催化剂与... 李林,林坚,李筱玉,... - 《Chinese Journal of Catalysis》 被引量: 0发表: 2016年 微量热技术测量担载型催化剂的吸附/反应能量并与反应性能...
The Sabatier principle has been applied by considering the key role of the adsorption strength of one intermediate in each case: a dimetallacycle and a single H atom, respectively.Nanoparticles in Catalysisdoi:10.1002/9783527821761.ch15Iker del Rosal...
Here, we discuss one approach, which is well-known within inorganic catalysis, but essentially unexploited in biotechnology. Specifically, we review examples of linear free-energy relationships (LFERs) for enzyme reactions and discuss how LFERs and the associated Sabatier Principle may be implemented ...