RuHCl(CO)(PPh3)3-Catalyzed Reductive Dimerization of α,β-Unsaturated Aldehydes Leading to α-Hydroxymethyl Ketonesruthenium enolatesaldol reactionα-hydroxymethyl ketonesα,β-unsaturated aldehydestransfer hydrogenationThe reductive dimerization α,β-unsaturated aldehydes to give saturated ketones was achieved...
An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl(CO)(PPh3)3. When primary unsaturated alcohols were treated with a catalytic amount of RuHCl(CO)(PPh3)3in benzene under reflux, dimerization reactions took place to giv......
摘要: We first report the direct ortho C-H amidation of arenes with azides by using a novel and inexpensive RuHCl(CO)(PPh3)3 catalyst. The reaction proceeds efficiently in high yield over a broad range of substrates without requirement of any additional silver salt or additive....
求助RuHCl(CO)(PPh3)3和RuCl2(PPh3)3的XRD粉末衍射图，PDF卡片里找不到，CA里找了很久也没找见，...
ChemInform Abstract: RuHCl(CO)(PPh3)3-Catalyzed -Alkylation of Ketones with Primary Alcohols.ketones (benzene compoundsC‐C bond formationpolyphenylalkane derivativesThe alkylation with aliphatic alcohols is feasible by addition of phenanthroline [cf.(V) and (VII)].doi:10.1002/chin.201303064...
The highly chemoselective transfer-hydrogenation of α,β-unsaturated ketones to give saturated ketones was achieved using RuHCl(CO)(PPh3)3 as a catalyst. In addition to α,β-unsaturated ketones, other enones, containing a remote C=C bond, were also reduced to give saturated ketones in good ...
Takashi Kuwahara,Takahide Fukuyama,Ilhyong Ryu.RuHCl(CO)(PPh3)(3)-Catalyzed alpha-Alkylation of Ketones with Primary Alcohols. Organic Letters . 2012Takashi Kuwahara,Takahide Fukuyama,Ilhyong Ryu.RuHCl(CO)(PPh3)(3)-Catalyzed alpha-Alkylation of Ketones with Primary Alcohols.Organic Letters. 2012...
Alcohol Ru RuHCl(CO)PPh3) dehydrogenation oxidat esterMilstein, D
Mixed﹍igands hydride complexes [RuHCl(CO)(PPh3)2{P(OR)3}] (2) (R = Me, Et) were prepared by allowing [RuHCl(CO)(PPh3)3] (1) to react with an excess of phosphites P(OR)3 in refluxing benzene. Treatment of hydrides 2 first with triflic acid and next with an excess of ...
Takahide D,Fukuyama T,Horiguchi J,et al.RuHCl(CO)(PPh3)3-catalyzed chemoselective transfer-hy-drogenation of enones leading to saturated ketones.Synlett. 2006Takahide D, Fukuyama T, Horiguchi J, et al. RuHCl( CO ) ( PPh3 ) 3 -catalyzed chemoselective transfer-hydrogenation of enones leading...