Bergman, N., Thapper, A., Styring, S., Bergquist, J. & Shevchenko, D. Quantitative determination of the Ru (bpy) 3 2+cation in photochemical reactions by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Anal. Methods 6, 8513-8518 (2014)....
Ru(bpy)32+2+ SurfaceCECTetracationic pyrene derivatives (Py4+) and dicationic tris(bipyridine)ruthenium(II) (Ru2+) were hybridized on a synthetic clay (SSA) surface; the hybrid is denoted as Py4+/Ru2+/SSA. The photochemical properties of the Py4+/Ru2+/SSA system, especially the ...
The ECL emission of Ru(bpy)32+alone is rather weak in solution. Therefore, in order to obtain high sensitivity, it is essential to find effective ways to enhance the ECL intensity of Ru(bpy)32+. Hitherto, researchers have explored a variety of ways to enhance the ECL emission of Ru(bpy...
levels slightly but upholds both the level separation as well as the near-degeneracy of the E states. An explicit H2O-[Ru(bpy)3]2+cluster (Fig.2right column) continues this trend, despite the fact that lower intrinsic symmetry is assumed in the computational method. Even when the number of...
16 October 2015 Quantitative Detection of DNA Yong-Ping Dong1,2, Ting-Ting Gao1,2, Ying Zhou1,2, Li-Ping Jiang1 & Jun-Jie Zhu1 In the present paper, we report that CdSe quantum dots (QDs) can act as the coreactant of Ru(bpy)32+ electrogenerated c...
Herein, for the first time, the electrochemiluminescent sensor based on Ru(bpy)3 2+-modified electrode using dopamine as an adhesive was successfully developed. After halloysite nanotube slurry was cast on a glassy carbon electrode and dried, an alkaline dopamine solution was added on the electrode...
Intramolecular stacking interactions in mixed ligand complexes formed by copper(II), 2,2′-bipyridine or 1,10-phenanthroline, and monoprotonated or deproto... The stability constants of the 1:1 complexes formed between Cu 2+ or Cu(Arm) 2+, where Arm=2,2′-bipyridine (Bpy) or 1,10-ph...
[PtEnTpy] + , [RuBpy 3 ] +2 , and NB + , (En is ethylenediamine; Ppy, Bt, Tpy are α-deprotonated forms of 2-phenylpyridine, 2-phenylbenzothiazole, and 2-(2′-thienyl)pyridine, respectively; Bpy is 2,2′-bipyridyl, and NB + is Nile blue) ions, which exhibit intense ...
40 Confocal microscopy images of mouse osteoclast cells treated with the ruthenium-caged inhibitor 56 (A–D) or cis-[Ru(bpy)2- (MeCN)2](PF6)2 (E–H). Cells were pre-incubated with either complex (0–1000 nm) for 30 min at 37 C in the presence of cathepsin B inhibitor CA074Me ...
Taking advantage of the strong chelating ability of bipyridine, we designed the 2D COF-205 structure by integrating 2,2′-bipyridine-5,5′-dialdehyde (Bpy-DA) as a building block. Interestingly, compared to RuO2, the delocalized crossed π-conjugation systems are constructed in COF-205-Ru by...