[RhCl(CO)2]2 reacts with o-(diphenylphosphino)benzaldehyde (PCHO) to afford a monocarbonylated rhodium(I) complex containing P-monodentate PCHO, trans-[RhCl(CO)(PCHO)2] (1) while [RhCl(COD)]2 undergoes the oxidative addition of one PCHO, with displacement of 1,5-cyclooctadiene, and ...
分子量717.50400 精确质量716.18700 LogP13.44380 [RhCl(cis-cyclooctene)2]2英文别名 [(cis-cyclooctadiene)2Rh(μ-Cl)]2 [rhodium(I) bis(cis-cyclooctene)Cl]2 [RhCl(coe)2]2 [RhCl(cod)2]2 [RhCl(cyclooctene)2]2 [(cis-cyclooctene)2RhCl]2...
2016年Martin Kotora课题组报道了在[Rh(cod)2BF4]/dppe催化下,二苯烯C-C键断裂后插入腈类化合物得到9-取代菲啶。 【 Synthesis2016, 48, 987–996】 2015年Albert Padwa等人报道了α-重氮丙二酸酰胺酯作为底物分别用Rh2(esp)2和Rh2(OAc)4催化分别会进行C-C键活化的 Buchner反应 得到环庚-2,4,6-三烯和...
(pyrazine)[RhCl(COD)]2 C20H28Cl2N2Rh2, β结构式 常用名 (pyrazine)[RhCl(COD)]2 C20H28Cl2N2Rh2, β 英文名 (pyrazine)[RhCl(COD)]2 C20H28Cl2N2Rh2, β CAS号 85528-97-8 分子量 565.10300 密度 N/A 沸点 N/A 分子式 C20H20Cl2N2Rh2 熔点 N/A MSDS N/A 闪点 N/A ...
Issue 2 (Feb 2010) , pp. 1-210 Issue 1 (Jan 2010) , pp. 1-100 Volume 64 (2009) Issue 11-12 (Dec 2009) , pp. 1215-1661 Issue 10 (Oct 2009) , pp. 1093-1214 Issue 9 (Sep 2009) , pp. 989-1092 Issue 8 (Aug 2009) , pp. 1-988 Issue 7 (Jul 2009) , pp. ...
Zirconocene symp issue: Vinylzirconocene [RhCl(cod)]2 cat Michael add crotonate enoate vinylationHanzawa, Y
Rh [RhCl(cod)]2 Binap cat unactivated alkyne isomerization 1,3-dieneHayashi, T
ChemInform Abstract: Synthesis of [RhCl(CO)(cyclopentadienone)]2 from [RhCl(cod)]2 and a 1,6-Diyne under CO: Application to Rh(I)-Catalyzed Tandem [2 + 2 + 1] Carbonylative Cycloaddition of Diynes and Claisen Rearrangement.cycloalkylphenyl derivatives...
Synthesis of [RhCl(CO)(cyclopentadienone)]2 from [RhCl(cod)]2 and a 1,6-diyne under CO: application to Rh(I)-catalyzed tandem [2+2+1] carbonylative cycloaddition of diynes and Claisen rearrangementLeeS.FukumotoY.ChataniN.ingentaconnectChemical Communications Royal Society of Chemistry...
We determined the structure of [Rh(i)Cl(CO)(cpd)]2, which was formed by the reaction of [Rh(cod)Cl]2with a 1,6-diyne under CO. In addition, based on determination of the structure of the [Rh(i)Cl(CO)(cpd)]2complex, we identified a new catalytic tandem reaction—the Rh-...