It was established by chemical degradation that RhCl* 3HO catalyzed titration with HTO occurred with virtually 100% regioselectivity at the ortho-positions of benzamide as well as various anilides and benzoic acid. While titration has not been found in the alkyl C-H bond in anilide molecules, ...
, 3H2O in HC(OEt)3 for the hydroformylation of alkenes: effect of P(OPh)3 on the selectivityAuthor links open overlay panelBassam El AliShow more Add to Mendeley Share Cite https://doi.org/10.1016/j.catcom.2003.10.003Get rights and contentAbstract A new catalytic system formed of RhCl...
RhCl3 center dot 3H(2)O-Catalyzed Regioselective C(sp(2))-H Alkoxycarbonylation: Efficient Synthesis of Indole- and Pyrrole-2-carboxylic Acid Estersindole-2-carboxylic esterspyrrole-2-carboxylic estersC-H activationalkoxycarbonylationrhodiumThe C-2-selective C-H alkoxycarbonylation of indoles with ...
This paper reports the quantitative studies of the water gas shift reaction catalysis by homogeneous solution of RhCl3 . 3H(2)O in aqueous piperidine, 2/8, v/v. This system is stable, low active catalyst displaying turnover frequencies for H-2 production (TF(H-2)) of about 19 moles H...