2018年Teruyuki Kondo等人报道了在[RhCl(η4-1,5-cod)]2催化下环丙烯酮C-C键活化开环后插入烯烃或炔烃的反应。 【 Synlett2018, 29, 717–722】 2016年Martin Kotora课题组报道了在[Rh(cod)2BF4]/dppe催化下,二苯烯C-C键断裂后插入腈类化合物得到9-取代菲啶。 【 Synthesis2016, 48, 987–996】 2015...
ChemInform Abstract: Reactions of α‐Diimino Ligands with the Chloro‐Bridged Dimer (RhCl(COD))2 (COD: 1,5‐Cyclooctadiene).organo‐rhodium compoundschemical equilibria, complexation equilibriaThe bridge-splitting reactions in (I) by α-diimino ligands (II) lead to different equilibria mixtures ...
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2018年Teruyuki Kondo等人报道了在[RhCl(η4-1,5-cod)]2催化下环丙烯酮C-C键活化开环后插入烯烃或炔烃的反应。 【 Synlett2018, 29, 717–722】 2016年Martin Kotora课题组报道了在[Rh(cod)2BF4]/dppe催化下,二苯烯C-C键断裂后插入腈类化合物得到9-取代菲啶。 【 Synthesis2016, 48, 987–996】 2015...
The reactions of α-diimino ligands N- N′ [ N- N′= 2,2′-bipyridine (bipy), C 5H 4N 2 CH NR (R= C 6H 4OMe- p, PyCa), RN CH CH NR (R=C 6H 4- OMe- p, DAB)] with [RhCl(COD)] 2 give rise to stoichiometry, solvent, ligand, and temperature dependent equilibria. ...
Unlike previously studied neutral and cationic Rh(I) precatalysts such as [{Rh(μ-Cl)(1,5-cod)}2] and [Rh(1,5-cod)2]OTf (1,5-cod = 1,5-cyclooctadiene, C8H12, OTf = OSO2CF3) with weakly electron-donating ligands at the metal center, which are reduced to catalytically active ...
Treatment of [NEt4][Rh(cod)η5-7,8-C2B9H9Me2)] (cod = cyclo-octa-1,5-diene) in THF with [CPh3][BF4] affords the complex [Rh(1–3 : 5,6-η5-C8H11)(η5-7,8-C2B9H9Me2)], the structure of which has been established by X-ray diffraction. The nido-7,8-C2B9H9Me2 ...
Trisubstituted silanes, HSiR 3- n X n (R = Me or Et, X = Cl, OEt, or Ph; n = 0–3) oxidatively add to the complex [RhCl(cod)(1-hexene)] (cod = cycloocta-1,5-diene) to yield [RhCl(cod)(1-hexene)(H)(SiR 3 )] [( 1 )]. Subsequent steps of hydrosilylation follow, i...
Synthesis and Crystal Structure of the Complexes [(Me 2 PhP) 3 Cl 2 Re≡N-RuCl 2 (C 6 H 6 )] and [(Me 2 PhP) 3 Cl 2 Re≡N-RhCl(COD)] The heteronuclear complex [(Me 2 PhP) 3 Cl 2 Re≡N-RuCl 2 (C 6 H 6 )] ( 1 ) is obtained by the reaction of [ReNCl 2 (...
The RhCl(amine){P(OPh) 3 } 2 complexes were obtained in the reactions of [Rh(μ-OMe)(cod)] 2 , [Rh(μ-Cl)(cod) 2 (cod = cycloocta-1,5-diene) or RhCl(CO){P(OPh) 3 } 2 with amines. CO substitution by amines RhCl(CO)(PR 3 ) 2 complexes [PR 3 = P(OMe) 3 , P(...