Draw all possible resonance structures for the following cation, and indicate which structure makes the largest contribution to the resonance hybrid.Draw the Lewis structure for NO_3^-. What are the molecular and electron geometries? Does this molecule have ...
geminal hyperconjugation, stabilizations in strained cyclic geometriesreading donor–acceptor interactions indirectly, alternative NBONRT formulation of resonance, closely (but not exactly) to Pauling'sSummary This chapter contains sections titled: The natural Lewis structure perturbative model Second-order ...
2012, 13 15436 the X-ray crystallographic structures were used, while the RMSD is more than 10 ppm for the optimized geometries at the B3LYP/6-31G(d) level. Although we could not isolate the error due to the structural uncertainties in the X-ray crystallography, the popular GIAO-B3LYP/6...