Nam, Pham CamNguyen, Minh ThoESChemical PhysicsNam, P. C.; Nguyen, M. T. The Se-H bond of benzeneselenols (ArSe-H): Relationship between bond dissociation enthalpy and spin density of radicals. Chem. Phys. 2013, 415, 18-25.
What is the relationship between the lonization energy of an anion with a-1 charge, such as F and the electron affinity of the neutral atom, F? Ionization enthalpy and Electron Affinity: Ionization enthalpy is defined as the energy ...
in theTg-scaled inverse-temperature range between 0 and 1, corresponding toTg/T∞andTg/Tg, respectively. The distinct nature of the viscosity curves of different glasses can then be primarily described by the convex curvature of the log10ηvs.Tg/Tplot. This curvature can be further quantified...
These results relate to the O-H bond dissociation enthalpy of the phenolic hydroxyl group in phenolic acids and the values of proton affinity and electron transfer enthalpy (ETE) involved in the electron donation ability of functional groups. In addition, we speculated that HAT, SET-PT, and SP...
Thus, for applications of LaCrO3 based compounds as interconnectors within an SOFC, no structural phase transition should occur between room temperature and the SOFC operating temperature. However, the phase transition temperature in La1−xCaxCrO3 is observed to increase with increase of the Ca ...
The electrocatalytic activity is to a large extent determined by the binding strength between the reaction intermediates and the catalyst surface, that is, the binding energy. Empirically, an ideal catalyst should be able to adsorb the intermediate with an optimal binding energy that is neither to...
The relationship between radical stability and bond dissociation enthalpy (BDH) is reexamined. It is shown that relative stabilization energies of radicals are not equal to relative BDH values. Net stabilization energies of radicals, SE0[R, RX] are defined relative to the R components of closed ...
Mechanism analysis showed that the highest occupied orbital energy, the most negative and positive Milliken charge were the main quantitative parameters affecting PCN flame retardancy. PCN flame retardancy gradually decreased as the number of Cl atoms increased. The level of similarity between the ...
the insertion of potassium into the iridium oxide and the formation of the birnessite phase is accompanied by the reduction of Ir back to an oxidation state comprised between 5 + (α-Li1IrO3) and 4 + (α-Li2IrO3). Hence, upon reaction with water, the catalyst is reduced, thi...
chemical bondhigher heating valuebiomass elemental compositionbiofuels dataThe gross calorific value of biomass is an important parameter for its applications for energy purposes. It represents the enthalpy of the complete combustion of a fuel, including the latent heat of water formed by the process....