Introduction Reduction in organic reaction Removal of oxygen Addition of hydrogen Gain of electrons Hydrogenation : catalyst CH =CH + H CH 2 2 2 3 CH3 Hydrogenolysis: catalyst ArCH2 NMe2 + H2 ArCH3 + HNMe2 Types of reduction The addition of electrons OCH3 OCH3 OCH3...
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Shono T,Ohmizu H.A novel chain reaction induced by cathodic reduction, addition of trichloromethyl anion to aldehydes or vinyl acetate.Tetrahedron Letters. 1981Shono T,Ohmizu H.A novel chain reaction induced by cathodic reduction, addition of trichloromethyl anion to aldehydes or vinyl acetate. ...
The oxygen reduction reaction (ORR) is an electrochemical process of the utmost importance in energy conversion and storage, corrosion and chemical technologies. The ORR plays a major role in biological processes (such as respiratory biochemical chain reactions) and is being incorporated into numerous ...
Ammonia (NH3) is essential for modern agriculture and industry and is a potential energy carrier. NH3 is traditionally synthesized by the Haber–Bosch process at high temperature and pressure. The high-energy input of this process has motivated research
but the reaction takes place in an aqueous solution instead of an organic solvent. This method is advantageous for the synthesis of water-stable MOFs. Microwave synthesis involves the use of microwave radiation to heat the reaction mixture and promote the formation of MOFs. This method is rapid ...
Reactions performed under N2 atmosphere at 100 °C using 2 mmol of (E)-3-phenyl-2-propen-1-ol (0.1 M in glycerol). [Substrate]:[Ru] ratio = 100:5. b Determined by 1H NMR spectroscopy from the crude reaction mixture after extraction with Et2O. The differences between conversion of (E...
Electrocatalytic CO2 reduction reaction (CO2RR) is an attractive way to simultaneously convert CO2 into value-added fuels and chemicals as well as to store
Here we employ a library of protic ionic liquids in an interfacial layer on platinum and gold to alter local proton activity, where the intrinsic oxygen-reduction reaction (ORR) activity is enhanced up to fivefold, exhibiting a volcano-shaped dependence on the pKa of the ionic liquid. The ...
Control over the architectural and electronic properties of heterogeneous catalysts poses a major obstacle in the targeted design of active and stable non-platinum group metal electrocatalysts for the oxygen reduction reaction. Here we introduce Ni3(HITP