Reduction(ODtbp = O-2,6-tBu2C6H3) reacts in a 1:1 ratio with the isocyanide CN-Xyl (Xyl = 2,6-Me2C6H3) to form the pseudo-tetrahedral 4-coordinate adduct with νCN 24 cm−1 higher compared to the free isocyanide. Uranium(III) complexes with bulky ligands UX3Stephen M. ...
WENZEL, MATTHIAS ET AL: "New indigoid compounds by reduction of bis-imidoylchlorides of oxalic aci - a further evidence for dimeric isocyanides?" MONATSHEFTE FUER CHEMIE (1999), 130(11), 1373-1382, 1999, XP002221654Wenzel, et al., " New Indigoid Compounds by Reduction of Bis-Imidoyl...
New efficient synthesis of 4-aminocarbonyl substituted 4H-3,1-benzoxazines by a Passerini 3CC/Staudinger/aza-Wittig sequence 伪-Acyloxy-carboxamide azides 1, obtained from Passerini reaction of easily accessible o-azidobenzaldehyde with isocyanides and carboxylic acids, reacted w... P He,J Wu,YB...
A singly bonded amido-distannyne: H2 activation and isocyanide coordination Chem. Commun., 50 (2014), pp. 2321-2323 CrossrefView in ScopusGoogle Scholar 50 T.J. Hadlington, M. Hermann, J. Li, G. Frenking, C. Jones Activation of H2 by a multiply bonded amido–digermyne: evidence for ...
Engineering hollow and porous platinum nanostructures using biomolecular templates is currently a significant focus for the enhancement of their facet-dependent optical, electronic, and electrocatalytic properties. However, remains a formidable challenge
Reaction of a ditantalum hydride complex with isocyanide is reported. The hydride complex underwent single and double isocyanide insertion into Ta–H bonds, giving iminoformyl and imine-iminoacyl complexes. The transformation of the iminoformyl complex into the amido-carbyne complex was also observed....
The reaction of the unsaturated anion [Re 3 (μ-H) 4 (CO) 9 (NCMe)] − with cyclohexylisocyanide gives the novel unsaturated anion [Re 3 (μ-H) 4 (CO) 9 (CNC 6 H 11 ) − . By reaction of this species with dimethylphenylphosphine a saturated compound is obtained, [Re 3 (...
Using a cross-over experiment the existence of key intermediates corresponding to dimeric isocyanides could be verified.doi:10.1007/PL00010197Matthias WenzelFrank LehmannRainer BeckertWolfgang GuntherHelmar GorlsSpringer-VerlagMonatshefte fur ChemieWENZEL, MATTHIAS ET AL: "New indigoid compounds by reduction...
Reactions of excess triarylarsine with pentakis(alkylisocyanide)cobalt(II) in EtOH or CH2Cl2 have produced complexes of the form [Co(CNR)4(AsR3)2]X2, where X = C1O4, BF4; AsR3 = AsPh3, As(C6H4Me-ρ)3; CNR = CNC6H11, CNCHMe2, CNCH2Ph, CNC4H9−n . Magnetic susceptibilities...
Dialkylated tosylmethyl isocyanides have been conveniently reduced to the corresponding hydrocarbons with lithium in liquid ammonia. This process has been successfully utilised in the synthesis of (Z)-9-tricosene - a sex pheromone of common house fly....