Ethylamine involved in the adduct was proposed to be the reduction product of acetonitrile and this was confirmed using deuterated acetonitrile. Other nitrile-containing compounds tested, including isobutyronitrile and benzonitrile, also formed the adduct ions of the respective amine forms under (+)ESI-...
NitrileBorohydride reductionFunctional pendant armsProtonationThecis-octahedral complex [NiL2](ClO4)2·H2O (1) (L2=C-racemic-1,8-bis(N-2-aminoethyl)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane), bearing two coordinatedN-CH2CH2NH2pendant arms, has been prepared by a ...
Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions. Nat. Commun. 3, 1254 (2012). Article CAS PubMed Google Scholar MacKay, B. A., Johnson, S. A., Patrick, B. O. & Fryzuk, M. D. Functionalization and cleavage of coordinated dinitrogen via ...
Aus Nitrilen (I) erhlt man mit Tetrabutylammoniumboranat (II) die primren Amine (III).doi:10.1002/chin.198109152T. WAKAMATSUH. INAKIA. OGAWAM. WATANABEY. BANJohn Wiley & Sons, LtdChemischer InformationsdienstWakamatsu, T.; Inaki, H.; Ogawa, A.; Watanabe, M.; Ban, Y. An Efficient ...
1.02.1.3.2 Reduction of nitriles to methyl groups using hydride reagents The direct reduction of an alkylnitrile to the corresponding hydrocarbon with a hydride reagent has not been reported as of early 2000. However, it is possible to achieve such a transformation through a two-step sequence....
Gambarotta, S. & Scott, J. Multimetallic cooperative activation of N2 .Angew. Chem. Int. Ed.43, 5298–5308 (2004). ArticleCASGoogle Scholar Hidai, M. & Mizobe, Y. Research inspired by the chemistry of nitrogenase—novel metal complexes and their reactivity toward dinitrogen, nitriles, and...
Further reduction can take place by addition of H2 to generate the corresponding amide hydride derivatives [(dippe)Rh]2(μ-H)(μ-NHCH2R′); this represents an overall stoichiometric reduction of a nitrile to a coordinated amide at a binuclear centre. These same amido-hydride complexes can be...
to a toluene solution of amide 1a (1.0 equiv.), Vaska’s complex (0.05 mol%), and B(C6F5)3 (5 mol%), the expected deoxygenative reduction proceeded smoothly at room temperature for 30 min to give amine 2a in 99% yield (Table 1, entry 1). Further screening of reaction conditions...
INTRODUCTION While no pretense is made to include all of the litera- This review covers solely the electrochemical reduc- tion of organic compounds at the cathode. Other related types of reduction such as polarographic reduction (360) are not discussed, nor is the interesting area of anodic ...
Green and convenient protocols for the efficient reduction of nitriles and nitro compounds to corresponding amines with NaBH4 in water catalyzed by magneti... NanocatalystReduction of nitrile and nitroAmineNaBH4WaterGreen chemistryIn this study, firstly, CuFe2O4 nanoparticles were prepared by a simple...