RadicalsSingle electron transferVisible lightThe one-electron reduction (OER) can profoundly affect the structure and reactivity of organic compounds. OER induced radical decarboxylative functionalizations of redox-active esters have gained wide concerns in this century. In this review, we present recent ...
thiol is also one of the most targeted sites in post-translational protein modification (Fig.1a)21,22,23. Inspired by the versatile reactivity of thiols, we conceived that, based on the feedstock of abundant carboxylic acid, a decarboxylative thiolation of acid-derived redox-active esters (RAEs...
Qin, T. et al. A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents.Science352, 801–805 (2016). CASPubMedPubMed CentralGoogle Scholar Murarka, S.N-(Acyloxy)phthalimides as redox-active esters in cross-coupling reactions.Adv. Synth. Catal.360, 1735–1...
ChemInform Abstract: A General Alkyl-Alkyl Cross-Coupling Enabled by Redox-Active Esters and Alkylzinc Reagents. A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents. Science. 2016; 352:801-805. DOI: 10.1126/science.aaf6123 [PubMed: 27103669]Qin, T.; ...
aThe mono- and polyacrylates and -methacrylates of dihydric and polyhydric alcohols are the preferred principal monomers and cross-linking agents as far as they meet the above criteria. Suitable alcohol moieties in such esters other than those mentioned above include mannitol, sorbitol, and other al...
redox-active estersAn efficient method for construction of C–N bonds is reported here. The iron-catalyzed azidation of N-hydroxy phthalimide (NHP) esters provides a convenient approach for the synthesis of carbamoyl azides with good substrate scope and functional group tolerance. Both aryl carbon...
Thanks to metal- and catalyst-free electrochemical conditions in an undivided cell, a series of readily available redox-active N-(acyloxy)phthalimide esters led to an efficient and highly stereoselective addition (85鈥鈥to 95鈥鈥r) of putative radical species to chiral (racemic and enantioenriched)...
Copper-catalyzedDecarboxylativeUnsaturated carboxylic acidsRedox-active estersThe first photoinduced copper-catalyzed dual decarboxylative cross-coupling of α,β-unsaturated carboxylic acids and redox-active esters has been developed. This reaction enabled C(sp)–C(sp) bond formation, which afforded a ...
Poly(amine esters) Derived from Diethyl 1,4-Cyclohexanedione-2,5-dicarboxylate. Macromolecules 1975, 8, 121–127. [Google Scholar] [CrossRef] Ueda, M.; Kino, K.; Hirono, T.; Imai, Y. Synthesis of Polyenamines by Vinylogous Nucleophilic Substitution Polymerisation of 2,2’-Disubstituted Bis...
Described here is an approach to employ tandem photoredox and copper catalysis to enable the cross coupling of alkyl N﹉ydroxyphthalimide esters, readily derived from alkyl carboxylic acids, with benzophenone imines. Hydrolysis of the coupling products furnish alkylated primary amines. Primary, secondary...