4-Nitrophenylacetic acid, when dissolved in aqueous methanolic alkali, undergoes a redox-type dimerization leading to the formation of 4,4′-dioxaloazobenzene and the corresponding azoxy-compound. Structures are proven by interconversion and synthesis. The relative amounts of products are closely ...
The oxidizing and reducing character of various exchanged L zeolites has been studied by EPR spectroscopy via the formation of perylene and tetracyanoethylene ion radicals, respectively, and correlated with the acido-basic properties of zeolites. In the series of alkaline L forms the reducing characte...
Odeh IN, Francisco JS, Margerum DW (2002) New pathways for chlorine dioxide decomposition in basic solution. Inorg Chem 41:6500–6506. doi:10.1021/ic0204676 Article CAS Google Scholar Page MM, Page CL (2002) Electroremediation of contaminated soils. J Environ Eng – ASCE 128:208–219. do...
Structure, conductivity and redox stability of solid solution Ce1−xCaxVO4 (0 ≤ x ≤ 0.4125) A-site-substituted cerium orthovanadates, Ce 1 x Ca x VO 4 , were synthesised by solid-state reactions. At room temperature, the solid solution limit in Ce 1 x Ca x VO 4 series is at ...
and the electrode surface (in this case silicon). This result is at variance with respect to the case of an alkyl SAM functionalized electrode surface (1decanethiol on Au), but featuring the ferrocene in bulk solution: in this case the Faradaic current is almost zero although the distance ...
Hydroxylamine forms strong color complexes with ninhydrin and Nessler solution, two of the standard reagents for ammonia. In the case of ninhydrin, ammoniu... WN Fishbein - 《Analytica Chimica Acta》 被引量: 6发表: 1967年 Nitrate/nitrite chemistry in NaNO/sub 3/-KNO/sub 3/ melts redox reac...
1、氧化还原反应(REDOX reaction)The basic definitionThe oxidation reduction reaction (REDOX reaction) is characterized by the corresponding changes in the chemical reaction of the elements before and after the reaction. The essence of the REDOX reaction is the gain or loss of the electron. The ...
The junction is formed by bringing into contact two mercury-drop electrodes whose surfaces are covered by COO(-)-terminated self-assembled monolayers (SAMs) and immersed in a basic aqueous solution of Ru(NH(3))(6)Cl(3). The electrical behavior of the junction, which is contacted at its ...
Redox signaling and cardiac function are tightly linked. However, it is largely unknown which protein targets are affected by hydrogen peroxide (H2O2) in cardiomyocytes that underly impaired inotropic effects during oxidative stress. Here, we combine a c