Oxidation-reduction reactions of the hexafluorides of the third row transition metals rhenium, osmium and iridium with a selected series of reductants have been studied. The results have shown that oxidant strength increases progressively from rhenium hexafluoride to iridium hexafluoride. The results of ...
The density functional theory (DFT) based hard-soft acid-base (HSAB) reactivity indices, including the electrophilicity index, have been successfully applied to many areas of molecular chemistry. In this work we test the applicability of such an approach to fundamental surface chemistry. We have co...
Reactivity of Transition Metals (Pd, Pt, Cu, Ag, Au) toward Molecular Hydrogen Dissociation: Extended Surfaces versus Particles Supported on TiC(001) or Sm... The reactivity of Pd4, Pt4, Cu4, Ag4, and Au4 clusters supported on TiC(001) toward molecular hydrogen dissociation has been studie...
Heteromultimetallic hydride clusters containing both rare-earth and d-transition metals are of interest in terms of both their structure and reactivity. Ho... Y Luo,T Shima,T Stewart,... - 《Nature Chemistry》 被引量: 49发表: 2011年 Electron-beam floating zone melting of refractory metals an...
Metal–metal bonded dinuclear compounds of Group 6 and 7 transition metals with several primary structural motifs and their reactivity toward halides and o... TE Concolino,JL Eglin - 《Journal of Cluster Science》 被引量: 18发表: 1997年 Reactivity of the metal-carbon bonds in the metallacycl...
Metal–metal bonded dinuclear compounds of Group 6 and 7 transition metals with several primary structural motifs and their reactivity toward halides and o... TE Concolino,JL Eglin - 《Journal of Cluster Science》 被引量: 18发表: 1997年 Reactivity of metal–metal bonds. IV. The reaction of...
THE SYNTHESIS AND CHARACTERIZATION OF NEW UNSYMMETRICALvic-DIOXIMES AND THEIR COMPLEXES WITH SOME TRANSITION METALS Synthesis and Reactivity in Inorganic and Metal-Organic ChemistryH. Bati, M. Taş, B. Bati, "The Synthesis and Characterization of New Unsymmetrical Vic... H Bati,M Taş,B Bati...
Metallic sodium is most often used for bench demonstrations of intense reactions because it is cheaper and easier to obtain. How can you tell which metal is more reactive? The metal reactivity chart shows which metals are more reactive. Metals on the top of the chart are the most reactive; ...
Metal–metal bonded dinuclear compounds of Group 6 and 7 transition metals with several primary structural motifs and their reactivity toward halides and o... TE Concolino,JL Eglin - 《Journal of Cluster Science》 被引量: 18发表: 1997年 加载更多0...
The surprising endoergic nature of the methane CH activation has been attributed to a large and unfavorable change in RuN bond dissociation energy upon conversion from Ru-amido to Ru-ammine. 展开 关键词: ruthenium(II amido complexes transition metals ...