[Reactivity and Structure: Concepts in Organic Chemistry] The Barbier Reaction and Related One-Step Processes Volume 31 || The Mechanism of the Barbier Rea... Blomberg,Cornelis 被引量: 0发表: 1993年 Reactivity and structure: Concepts in Organic Chemistry; Volume 26, Polyquinane Chemistry, Synthe...
ChemInform Abstract: REACTIVITY AND MECHANISM IN ORGANOGOLD CHEMISTRY. A FIRM FOUNDATION FOR FUTURE RESEARCHorganic chemistry, reviewdoi:10.1002/chin.197828344R. J. PUDDEPHATTJohn Wiley & Sons, LtdChemischer Informationsdienst
The text opens with a short overview of the way chemists understand chemical structure, and how that understanding is essential in developing a good knowledge of chemical reactivity and mechanism. The remainder of the text presents a mechanistic classification of modern organic chemistry, developed in...
reactivity, selectivity and mechanisms in the ground and excited states. This chapter presents such a mechanism, which is based on valence bond theory (VBT) and enables one to make predictions and outline the basic principles that govern reactivity, selectivity and mechanistic aspects of chemical ...
This chapter discusses recent computational studies of radical cations in the context of qualitative concepts of classical physical organic chemistry. It demonstrates how such basic concepts, such as conjugation and electronic state or even more fundamental notions of structure, bonding, and mechanism, ...
include 2-(3-indolyl)-Trp (31) [71], its hydration product, the dihydroindole-Trp conjugate 32 [72], and non-conventional adducts of Trp such as 1-(2-Trp)-3-(3-indole)propylene (33) or 1-(2-Trp)-1-(3-indole)propylene (34), for which the mechanism of formation remains unknown...
Systematic exploration of the mechanism of chemical reactions: the global reaction route mapping (GRRM) strategy using the ADDF and AFIR methods. Phys. Chem. Chem Phys 15, 3683–3701 (2013). Article CAS PubMed Google Scholar Bannwarth, C. et al. Extended tight-binding quantum chemistry ...
Several theories and rules have been proposed in the literature for the study of the reactivity and selectivity of DA reactions, namely the transition state theory (TST) and the frontier molecular orbital (FMO) theory. For many years, I have studied the molecular mechanism of DA reactions. An...
Ultimately,thebestwaytoachieveproficiencyinorganicchemistryistounderstandhowreactionstakeplace,andtorecognizethevariousfactorsthatinfluencetheircourse.Thisisbestaccomplishedbyperceivingthereactionpathwayormechanismofareaction.3-2-1.ClassificationbyStructuralChange First,weidentifyfourbroadclassesofreactionsbasedsolelyonthe...
A sophisticated, in situ solid-state NMR spectroscopy study showed that the ozonolysis of ethylene groups follows an entirely different mechanism than is normal for organic, molecular groups. Ultimately, this leads to the topotactic transformation of the PMO material. Only if silicon is not in the...