Reaction Rate Theory and Rare Events bridges the historical gap between these subjects because the increasingly multidisciplinary nature of scientific research often requires an understanding of both reaction rate theory and the theory of other rare events. The book discusses collision theory, transition ...
Book2017,Reaction Rate Theory and Rare Events Simulations PetersBaron Explore book Abstract Unimolecular reactionrate theory describes theisomerization, dissociation, or decomposition of a single reactant molecule or complex in the gas phase. Early work on unimolecular reactions was hampered by experimental...
Reaction Rate Theory and Rare Events Simulations Book2017, Reaction Rate Theory and Rare Events Simulations PetersBaron Explore book 1.1 Motivation for this book This book provides a broad introduction to the most powerful theories and computational methods for understanding the kinetics and mechanisms ...
The past–future (or predictive) information bottleneck framework introduced and developed in many forms8,9,10,11 involves implementing such neuronal models from an information theoretic basis that can originally be traced back to Shannon’s rate distortion theory. Here we interpret the RC in ...
Textbook concepts of diffusion-versus kinetic-control are well-defined for reaction-kinetics involving macroscopic concentrations of diffusive reactants that are adequately described by rate-constants—the inverse of the mean-first-passage-time to the re
//doi.org/10.1140/epjh/s13129-023-00060-5 Regular Article THE EUROPEAN PHYSICAL JOURNAL H The 50th anniversary of the coupled channels Born approximation (CCBA) and the coupled reaction channels (CRC) theories of nucleon transfer reactions (a unique interplay between theory, experiment and ...
For example, we were interested in determining whether a factors such as the polarity of sentiment, had an effect on the hazard rate for information flow survival. Put another way, does express- ing negative sentiment increase the lifetime of an infor- mation flow? This question can be posed...
While language models excel at forecasting adjacent words, predictive coding theory presents a preliminary explanation for this divergence. The human brain, on the other hand, consistently predicts a hierarchical structure of representations spanning a range of timescales. Using functional magnetic resonance...
The rate of an elementary step is determined by the difference between the rates of the forward and the reverse reactions: (3.42)r=r+−r− where r, r+, and r− are the rate of the step, the rate of the forward reaction and the rate of the reverse reaction, respectively. An el...
, Nv is the total number of volume-occupying components, qn is the specific volumetric rate of injection (+) or production (−) of component n, cn is the compressibility of volume-occupying component n, ct is the total compressibility, and p is the pressure. The solution scheme is as ...