ONOM,OKURA I.Onthereactionmechanism ofalkeneepoxidationwithMethylosinustrichosporium (OB3b)[J].Journalof MolecularCatalysis,1990,61(1):113-122.Ono, M., and I. Okura. 1990. On the reaction mechanisms of alkene epoxi- dation with Methylosinus trichosporium OB3b. J. Mol. Catal. 61:113-122...
3.5 系间窜跃机制 Mechanisms of Intersystem Crossing 16:15 3.6 辐射跃迁的基础理论 Basic Theory of Radiative Transitions 14:13 4.1 能量转移 Overview of Energy Transfer 09:08 4.2 敏化 Sensitization_ Introduction and Thermodynamics 13:30 4.3 Dexter能量转移 16:52 4.4 Förster共振能量转移 14:...
Reaction mechanisms for the liquid-phase epoxidation of alkenes are reviewed critically: the classical Prilezhaev reaction, catalytic epoxidation with participation of hydrogen peroxide and of organic hydroperoxides, reactions for the production of alkene oxides in the oxidation of unsaturated hydrocarbons,...
The latest chemistry news and research on reaction mechanisms, including kinetic studies, physical organic chemistry and biochemical mechanisms, from the Royal Society of Chemistry's magazine, Chemistry World
The model identifies a wide variety of classes of mechanism with outstanding accuracy, including mechanisms out of steady state such as those involving catalyst activation and deactivation steps, and performs excellently even when the kinetic data contain substantial error or only a few time points. ...
The mechanisms and kinetics of the reaction of a thiocyanato radical (NCS) with NO were investigated by a high-level ab initio molecular orbital method in conjunction with variational RRKM calculations. The species involved were optimized at the B3LYP/6-311++G(3df,2p) level, and their single...
reaction mechanisms"CO-free" carbonylation reactions, where synthesis gas (CO/H-2) is substituted by C1 surrogate molecules like formaldehyde or formic acid, have received widespread attention in homogeneous catalysis lately. Although a broad range of organics is available via this method, still ...
Several power law models and models based on assumed mechanisms successfully described the evolution of carbon oxides and water. The models that described the experimental data indicated that oxygen forms a reactive intermediate in a fast equilibrium reaction, and the formation of CO and CO2 proceeds...
Kinetics and mechanisms of oxygen transfer in the reaction of p-cyano-N,N-dimethylaniline N-oxide with metalloporphyrin salts. 2. Amine oxidation and oxygen transfer to hydrocarbon substrates accompanying the reaction of p-cyano-N,N-dimethylaniline N-oxide with meso-(tetraphenylporphinato)iron(III)...
For these investigation, the mechanisms of this reaction should be understood properly. Although the d(e,e^'p)n reaction is the simplest one, its mechanism remains to be checked at high Q^2: short distances are involved and, therefore, it is unclear what degrees of freedom (nucleonic or ...