The reaction has a rate constant 2.6 × 10−10cm3/sec and appears to produce both O2+and O+ as product ions, approximately in the ratio 5:3. The reactions of CO2+ with O2, and NO were also measured in the course of these experiments as well as the reactions of N2+ with O and ...
The values are 50% larger than those previously reported.doi:10.1016/0009-2614(94)00024-7Akira Masaki aShigeru Tsunashima aNobuaki Washida bChemical Physics LettersMasaki, A. S. Tsunashima N. Washida , Rate constant for the reaction of CH3O2 with NO , Chem. Phys. Lett. , 218 , 523 – ...
The rate constant for the reaction H + C2H5 has been measured directly at T = 150, 202, and 295 K and at P = 1.0 Torr He for all temperatures, and additionally at P = 0.5 and 2.0 Torr He at T = 202 K. The measurements were performed in a dischargefast flow system. The decay ...
Rate Constant for the Reaction of Hydroxyl Radical with Formaldehyde over the Temperature Range 228-36 K Absolute rate constants for the reaction OH + H2CO measured over the temperature range 228-362 K using the flash photolysis-resonance fluorescence techniqu... LJ Stief,DF Nava,WA Payne,......
The rate constant for the reaction of CH2Cl2 with OH was measured by the flash photolysis resonance fluorescence technique over the temperature range 277370 K to give the following Arrhenius expression: kDCM = ( ) × 10-12 exp{(944 ± 29)/T} cm3 molecule-1 s-1, where the uncertainties ...
Rate constants for the reaction deuterium atom + water-d2 .fwdarw. deuterium + hydroxyl-d by the flash photolysis-shock tube technique over the temperature range 1285-2261 K: results for the back-reaction and a comparison to the protonat... The absolute rate constant for the reaction of D...
The rate constant for the reaction of CH(a4Σ) with NO is (4.2 ± 0.7) × 10-11 cm3 molecule-1 s-1. Carbon monoxide interacts more slowly with CH(a4Σ), with a pressure independent rate constant of (8 ± 2) × 10-13 cm3 molecule-1 s-1. Only upper limits could be set for ...
Abstract We have measured the rate constants for the reaction of O + ions with NO from room temperature to 1400 K. The reaction is slow (k=8×10 −13 cm 3 s −1 ) at room temperature and the rate constant increases to 2.6×10 −12 cm 3 s −1 at 1400 ...
The rate constants are in good agreement with the previous flow drift tube measurements at the same translational temperatures. Any dependence of the rate constant on internal energy is therefore small.关键词: Reaction rate constants Flow rate measurement Flowing afterglow Transfer reactions Charge ...
(1985), Temperature dependence of the rate constant for the reaction OH + H2S in He, N2, and O2. Int. J. Chem. Kinet., 17: 1201–1214. doi: 10.1002/kin.550171106 Author Information Department of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300, Republic of China Publication...