Fig. 7: A radical clock experiment. From: Facile access to C-glycosyl amino acids and peptides via Ni-catalyzed reductive hydroglycosylation of alkynes In red are the formed bonds. Back to article page Nature Communications (Nat Commun) ISSN 2041-1723 (online) ...
To definitely resolve this controversy, theory must first address the actual systems that have been used by experiment, and that generated the controversy. This is done in the present paper, which constitutes the first extensive theoretical study of such two experimental systems, trans-2-phenyl...
Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory 2002, Chemical Reviews Dioxygen activation and methane hydroxylation by soluble methane monooxygenase: A tale of two irons and three proteins 2001, Angewandte Chemie - Internation...
In our experiment, a xenon lamp was used to photodissociate the 1,3-diphenyl-2-propanone (dibenzylketone, DBK) precursor to form the benzyl radical. Gas chromatography was then used to determine the relative concentrations of the organic products derived from the abstraction process, from which ...
The RPM model can reproduce both magnetic field and lithium effects. The comparison between period changes due to applied magnetic fields measured in the experiment25,\(\Delta _{expt-MF}\), and obtained by the RPM model,\(\Delta _{RPM-MF}\), where\(\Delta _{MF}\)is the difference be...
To definitely resolve this controversy, theory must first address the actual systems that have been used by experiment, and that generated the controversy. This is done in the present paper, which constitutes the first extensive theoretical study of such two experimental systems, trans-2-phenyl...
To definitely resolve this controversy, theory must first address the actual systems that have been used by experiment, and that generated the controversy. This is done in the present paper, which constitutes the first extensive theoretical study of such two experimental systems, trans-2-phenyl...