where [Ox] and [Red] are the concentrations of oxidizing and reducing agents and k is the rate constant. For photochemical initiation, intensity of light affects the rate and equation: (20)Ri=(d[M•]dt)i=2ΦIabs where Iabs is the intensity of the light absorbed and the constant Φ...
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Noureddine Barka, in Materials Research Bulletin, 2022 6.5 Sulfate radical-based AOPs In recent years, sulfate radical-based AOPs have attracted great interest owing to their own particular advantages, among them a high oxidation capacity, selectivity, and efficiency in oxidizing emerging compounds. ...
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The red arrows represent the vector of electron spin states. Upon light absorption, the primary electron donor undergoes electronic excitation to form the excited state P*. Within 25 ps, ET from P* to the primary electron acceptor A0 occurs, resulting in the formation of a radical pair in a...
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(in red).bThe EPR spectrum of the powder sample of22+at 183 K with the forbidden transition at the half magnetic field.cTemperature-dependent plots ofχMTfor the crystals of22+from 2 to 320 K (in black) with the fitting plot via the Bleaney–Bowers equation (in red).dTemperature...
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