doi:10.1002/jlac.199619961128DiradicalsSupercritical fluid reactionsO2 trappingReaction force fieldCage effectCope reactionvan der Waals Complexes, Intermediates in Unimolecular ReactionsWolfgangFakult R.Fakult RothFakult FrankFakult HunoldFakult John Wiley & Sons, LtdLiebigs Annalen ...
摘要: van der Waals Complexes, Intermediates in Unimolecular Reactions 关键词: Diradicals Supercritical fluid reactions O2 trapping Reaction force field Cage effect Cope reaction DOI: 10.1002/jlac.199619961128 年份: 1996 收藏 引用 批量引用 报错 分享 全部来源 求助全文 Wiley ...
范德华表面(van der Waals surface):不同原子范德华球相互重叠形成的表面;分子表面(molecular ...
状态方程对R134a摩擦理论黏度模型的影响分析
Mass-selective ground-state vibrational spectra of jet-cooled carbazole·R (R=Ne, Ar, Kr, and Xe) van der Waals complexes were obtained by populating ground-state intra- and intermolecular levels via stimulated emission pumping, followed by time delayed resonant two-photon ionization of the ...
ChemInform Abstract: Cationic Polymerization Within van der Waals Clusters of the Form (CH2= R)+ n (R: CH2, CF2, and CHCH3)mass spectra (organic substances)ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals....
from Ideal Gas Law Equation (Show calculation) [17] Percent error in R from the Ideal Gas Law Equation (Show calculation) [18] Universal Gas Constant, R, from Van der Waals Equation (Show calculation) l-atm/mol K [19] Percent error in...
The van der Waals equation of state is used to determine phase diagrams for a wide variety of binary fluid mixtures. The locus of the critical line in pressure-temperature-composition space is determined exactly by solving a set of equations with the aid of a computer. The van der Waals con...
(1993) it was shown that the localization of helium atoms around the heavy impurities in van der Waals clusters results in the freezing out of such clusters and in the formation of an impurity–helium solid phase. The suppression of the zero point vibration amplitude of helium atoms in this ...
Vf: free volume at T < Tg (Vf)T: free volume at T Tg Vt: total volume at T Tg V0: occupied volume (determined by van der Waals interaction + vibration) dV/dT): CTE of the glass- and rubber-state where f T f g f T Tg...