The pyro-electro-chemical coupling is on basis of product of the pyroelectric effect and the electrochemical effect, which can be proved by the observed intermediate reaction products of superoxide radicals (center dot O-2(-)) and hydroxyl radicals (center dot OH). The enhanced pyrocatalytic ...
Pyroprocessing and electrorefining Pyroprocessing takes the hard ceramic oxide pellets retrieved from light water reactors – around 95% of which is still uranium and another 1% is long-lived radioactive elements actinides while the rest is unusable fission products – and converts the oxide constit...
In addition to the pyro-catalysis of BaTiO3and hot electron catalysis of Au, thermoelectric effect could also contribute to the overall catalytic reaction of water splitting. Thus, we perform thermal calculation by COMSOL Multiphysics 5.5 to estimate the thermoelectric effect of Au/BaTiO3. A simplif...
−5, +5, +10, +15, +20 °C.gthe pseudo-first-order reaction kinetics of different temperature fluctuations. Electron paramagnetic resonance spectra (EPR) of radicalh•OH andi•O2-created by pyro-catalysis over different temperature range. Source data are provided...
Cyclic voltammetry and chronoamperometry data obtained in this study indicate that the deposition of Pt on plasma carbon increases its electrocatalytic activity toward ethanol oxidation reaction. ETC Santos,PG Toscano,GMC Cunegundes,... - 《Journal of Spectroscopy》 被引量: 5发表: 2015年 The ...
This paper describes the processes that are used and presents the chemical theory that was developed for quantitatively predicting the results of both chemical and electrotransport operations 展开 关键词: nuclear fuel cycle and fuel materials management of radioactive and non-radioactive wastes from ...
The reaction of primary and secondary amines with 2,4,6-triarylpyryliums is shown by C-13 NMR to proceed by fast ring opening to a vinylogous amide; in the case of primary amines this closes slowly to a pyridinium salt. The reaction in D... AR Katritzky,RTC Brownlee,G Musumarra - 《...
By a reaction with oxygen, La, Pr, Nd, Sm, Eu, and Gd were converted to their oxychloride form (REOCl) and Ce, Pr, and Y to their oxide form (REO2, RE2O3). Since these lanthanide oxides or oxychlorides are nearly insoluble to eutectic salt, they were all precipitated by a free...
The reaction mixtures were incubated at 37 1C for 30 min and terminated by adding 10 volume of loading buffer (5% sarkosyl, 0.0025% bromophenol blue, 25% glycerol). Reaction products were electrophoresed on a 0.7% agarose gel in Tris-acetate-EDTA running buffer containing ethidium bromide (...
To ensure efficient electron transport and biocompatibility, the QDs were capped with mercaptopropionic acid (MPA) via a ligand exchange reaction. Mn was used as part of the metal chalcogenide to create unique electronic states in the QDs structure, thereby enhancing its electrocatalytic activity. ...