The pentapeptide coordinates in a tetradentate manner with the metal ions via an S-atom on the methyonyl-side chain, two N-amide nitrogens, (after a deprotonation of gly1 and gly2 residues) and the primary NH2 nitrogen of Ntermini. The MN3S chromophores are distorted to near square planar...
Magnetic and spectroscopic data revealed complexes 13 to have octahedral geometry. IR spectra suggested that GFS ligand coordinated in mononegative tridentate mode (OOO) for 1 but in neutral bidentate mode (OO) for 2 and 3. In addition, HGly behaves as mononegative bidentate coordinated to Pt(...
resistive switching effect AislmthoosutglyhbHasfeOd2oins well recognized as a charge defect migra- tion14. Furthermore, it such as high thermal has been stability, shown that large band ghaapfnaiunmd hailughmbinaartreiser(HfofrOo2:xAylg2Oen3-dHifAfuOs)ioenx1h2i,1b5i,t16i.mYpert,otvhe...
Ph2P1(C6H4N1)(C7H4ClO1)(C7H8N2) (4-chloro-2-(((2-(diphenylphosphino)phenylimino)methylphenylate Ph2P1(C6H4N1)(C8H7NOO1) (2-(((2-(diphenylphosphino)phenylimino)methyl-4-methoxyphenylato) Ph2P1(C7H5N1)(C2H2O)N2(C6H4OH) (N-(2-(diphenylphosphinobenzylidene)-N-(2-hydroxyphenyl)glyci...
Studies of the spectra of copper dimethyl-glyoxime, nickel dimethylglyoxime and nickel ethylmethylglyoxime in various solvents. Talanta 1966, 13, 967–977. [Google Scholar] [CrossRef] Burger, K.; Ruff, I.; Ruff, F. Some theoretical and practical problems in the use of organic reagents in ...
4. Conclusions We have studied the three NiII, PdII and PtII complexes [M(Hdmg)2] (H2dmg = dimethyl- glyoxime) by density functional DFT and TD-DFT methods to explore the structural and IR and UV-vis absorption spectroscopic properties of the molecular species of these complexes. The ...