For the average first semester student, these distinctions come up the most in substitution reactions, where hydrogen bonding solvents tend to decrease the reactivity of nucleophiles; polar aprotic solvents, on the other hand, do not. There are 3 types of solvents commonly encountered: nonpolar, po...
In the case of Na‐ion chemistry, Pyr14TFSI appears very promising while the use of PyrH4TFSI is not applicable due to the lack of electrochemical stability below 1 V vs. Na/Na+.doi:10.1002/batt.201800073Arnaiz, MaríaHuang, Peihua...
Physical Chemistry of Ionic Liquids: Inorganic and Organic as Well as Protic and Aprotic. In Electrochemical Aspects of Ionic Liquids, 2nd ed.; Ohno, H., Ed.; John Wiley & Sons: Hoboken, NJ, 2011; pp 5-31.Angell, C. A.; Xu, W.; Yoshizawa-Fujita, M.; Hayashi, A.; Belieres, ...
We also tried corresponding aprotic methyl vinylacetate (MVA) following Procedure A, in which comparable activity is obtained but with obviously reduced comonomer incorporation (1.1 mol% vs. 2.1 mol%) andMw(15 kg/mol vs. 33 kg/mol) (entry 9 vs. 1). These intriguing trends lik...
Parallel developments in aprotic and protic ionic liquids:Physical chemistry and applications. Angell C A,Byrne N,Belieres J P. Accounts of Chemical Research . 2007Angell C A,Byrne N,Belieres J P.Parallel developments in aprotic and protic ionic liquids:Physical chemistry and applications. ...
Rate constants of acid-catalyzed hydrolysis of sucrose (S) to D-glucose and L-fructose have been determined at 25 °C by optical rotation measurements in aqueous mixtures of protophobic protic glycerol (GL), protophilic protic urea (UH), aprotic dioxane (D), and dipolar aprotic dimethyl ...
CHEN S.H. ET AL: ' The chemistry of taxanes: reaction of taxol and baccatin derivatives with Lewis acids in aprotic and protic media ' TETRAHEDRON vol. 49, no. 14, 02 April 1993, pages 2805 - 2828The Chemistry of Taxanes: Reaction of Taxol and Baccatin Derivatives with Lewis Acids in ...
Parallel developments in aprotic and protic ionic liquids: physical chemistry and applications. Acc Chem Res 2007;40:1228.Angell, C. A.,Byrne, N.,Belieres, J.-P.Parallel Developments in Aprotic and Protic Ionic Liquids:Physical Chemistry and Applications.Accounts of Chemical Research. 2007...
Angell CA, Byrne N, Belieres JP (2007) Parallel developments in aprotic and protic ionic liquids: physical chemistry and applications. Acc Chem Res 40:1228–1236Angell, C.; Byrne, N.; Belieres, J. Parallel developments in aprotic and protic ionic liquids: Physical chemistry and applications....
Physical chemistry of ionic liquids: Inorganic and organic as well as protic and aprotic. In Electrochemical Aspects of Ionic Liquids; Ohno, H., Ed.; John Wiley & Sons: Hoboken, New Jersey, 2011; pp. 5-33.Angell, C. A.; Xu, W.; Yoshizawa-Fujita, M.; Hayashi, A.; Belieres, J....