Solubility: insol hexane. Preparative Methods: metalation of methallyl alcohol with n-Butyllithium–Potassium tert-Butoxide. Handling, Storage, and Precautions: air, water, and temperature (greater than 0°C) sensitive.doi:10.1002/047084289X.rl122mCarlsonRobert MJohn Wiley & Sons, Ltd...
The formation of 2-oxopropyl-2-oxopropylidenediphenylphosphorane. Crystal and molecular structure of its lithium enolateorgano‐phosphorus compounds, isocyclic C derivativesstructure (organic substancesorgano‐lithium compoundsSubsequent dehydrobromination in the reaction of bromoacetone (I) and diphenyl...
Synthesis and reaction of [(TpiPr2)LnH 2 ] 3 (Ln = Y, Lu) with CO: Trinuclear cluster-bound propenolate en route to selective formation of propene. Cheng, Jianhua,Ferguson, Michael J.,Takats, Josef. Journal of the American Chemical Society . 2010...
COPOLYMERS OF 2,3-EPOXYPROPYL-A/2,3-EPITHIOPROPYL/-2-PROPENOLATES AND METHOD OF THEIR PREPARATIONMAROUSEK VLADIMIR ING. CSC.,CSLAZNICKA VLADIMIR RNDR.,CSBEDNAR BOHUMIL DOC. ING. CSC.,CS
Claisen rearrangement of methyl-3-aryloxy-2-(aryloxymethyl)prop-2-enoates (4) in refluxing N,N-diethylaniline gave 3-(2-hydroxyphenylmethylene) -3,4-dihydro-2H-1-benzopyran-2-ones (6) and 3-methoxycarbonyl-2H-1-benzopyrans(7).D
Reaction of lithium ja:math -enolates with the cobalt-complexed propynals gave the ja:math isomers, whereas lithium ja:math -enolates afforded the ja:math derivatives in a highly stereoselective manner.doi:10.1016/S0040-4039(01)93816-XChisato Mukai...
The direction of the reaction of propane-1,3-dichalcogenolates with 2,3-dichloroprop-1-ene in the system hydrazine hydrate-KOH depends not only on the conditions but to a greater extent on the chalcogen nature. Dipotassium propane-1,3-dithiolate and propane-1,3-diselenolate give rise to...
Effect of the chalcogen nature on the reaction of propane-1,3-dichalcogenolates with 2,3-dichloroprop-1-eneLevanovaE. P.Grabel’nykhV. A.VakhrinaV. S.RussavskayaN. V.AlbanovA. I.RUSSIAN JOURNAL OF ORGANIC CHEMISTRY C/C OF ZHURNAL ORGANICHESKOI KHIMII...
W.,Ha, D.-C.A highly diastereoselective synthesis of a 1-(3-methylcarbapenem intermediate using titanium enolate of 2’’’-hydroxypropiophenone. Tetrahedron . 2004Lee, Y.-S.,Choung W.-K.,Kim, K. H.,Kang, T. W.,Ha, D.-C.A highly diastereoselective synthesis of a 1-(3-methylcarba...
ChemInform Abstract: Substituted Lithium E‐3‐Lithio‐3‐tosyl‐2‐propenolates: Useful Intermediates in Organic Synthesisfuran derivativescleavage reactions, decomposition reactions, pyrolysisring closure reactionsoxidation, dehydrogenation, ozonolysissulfonamides (hydrazides, ureides) (benzene compounds...