Monometalated tribenzotriquinacene: exo and endo coordination of sodium and potassium with a rigid bowl-shaped hydrocarbon anionKlettJ.ingentaconnectChemical Communications Royal Society of Chemistry
185 Spherical nanoparticles were obtained when 1-butyl-3-methylimidazolium chloride [BMIM][Cl] was used, from disk-like nanoparticles observed in the control reaction without IL. Sabbaghan186 described the formation of uniform 2D ZnO nanostructures by the ionic liquid-assisted sonochemical metho...
Potassium tert‐Butoxide‐Catalyzed Selective Synthesis of 1,4‐Benzodioxepines via 7‐exo/7‐endo‐dig Cyclization of Alkynol: Experimental and DFT StudyBenzodioxepinesRegioselectiveDiastereoselectiveIntramolecular CyclizationBase Catalysis ReactionsA new method utilizing base catalysis is o...
Thiacalix[4]‐bis‐crown‐5 (L) was employed as a model host molecule, which shows both HSAB concept and endo/ exo ‐coordination modes. In the K+ complexations, a dinuclear complex [K2(L)](ClO4)2·CH3CN (1) as well as a mononuclear complex [K(L)][Pt(tht)Cl5] (2) (tht =...