A novel nanocomposite based on polyoxometalates-based metal–organic frameworks / reduced graphene oxide (PMG) can be used as an ideal platform for lithium-ion batteriesPMG nanocomposite demonstrates the advantages of polyoxometalates (POMs), metal–organic frameworks (MOFs) and RGO, thus shows the ...
LaPOM@MOFs doped with a low percentage of either mixed Eu3+/Tb3+ or Dy3+ as well as mixed Eu3+/Tb3+ and Dy3+ 2D coordination polymers were prepared using a hydrothermal synthesis, where pyridine-2,6-dicarboxylic acid was used as the organic linker, yielding four materials: Eu,TbPOM...
The design and synthesis of POMOFs/RGO nanocomposites might guide the development of new generation electrode materials for lithium-ion batteries.doi:10.1016/j.nanoen.2017.02.028Tao WeiMi ZhangPing WuYu-Jia TangShun-Li LiFeng-Cui ShenXiao-Li Wang...
To investigate the influence of POM species, temperature and counterions on the structures of POM-MOFs containing Cu-tda second building units (SBUs), six new complexes with various dimensionalities, e.g. three dimensional (3D) [Cu(H2tda)(H2O)2]4[SiW12O40]·12H2O (), two dimensional (...
metal N-heterocyclic multi-carboxylic acid frameworks not only enhance the thermal stability of compounds 2 and 3, but also introduce functionality inside their structures, thereby, realizing four approaches in the 1D hydrophilic channel used to engender proton conductivity in MOFs for the first time....
We have succeeded in constructing a metal–organic framework (MOF), [Cu(bpdc)(H2O)2]n (H2bpdc=2,2′-bipyridyl-3,3′-dicarboxylic acid, 1), and two poly-POM–MOFs (POM=polyoxometalate), {H[Cu(Hbpdc)(H2O)2]2[PM12O40]n H2O}n (M=Mo for 2, W for 3), by the controllable ...
Miras, H. N.; Vila-̀ Nadal, L.; Cronin, L. Polyoxometalate based open-frameworks (POM-OFs). Chem. Soc. Rev. 2014, 43 (16), 5679- 5699.Miras, H.N.; Vila-Nadal, L.; Cronin, L. Polyoxometalate based open-frameworks (POMOFs). Chem. Soc. Rev. 2014, 43, 5679-5699. [Cross...
Eu3+/Tb3+ and Dy3+ POM@MOFs and 2D coordination polymers based on pyridine-2,6-dicarboxylic acid for ratiometric optical temperature sensingLaPOM@MOFs doped with a low percentage of either mKaczmarek, A.JOURNAL OF MATERIALS CHEMISTRY. C...
We have succeeded in constructing a metal-organic framework (MOF), [Cu(bpdc)(H2O)2]n (H2bpdc=2,2′-bipyridyl-3,3′-dicarboxylic acid, 1), and two poly-POM-MOFs (POM=polyoxometalate), {H[Cu(Hbpdc)(H2O)2]2[PM12O40]⋅n H2O}n (M=Mo for 2, W for 3), by the ...
Encapsulating ionic liquids into POM-based MOFs to improve their conductivity for superior lithium storage†The PXRD patterns were collected on a D/max 2500 VL/PC diffractometer (Japan) equipped with graphite mono- chromatized Cu Ka radiation (l 1/4 1.54060 A˚). The FTIR spectra were ...