3. “Protic” Solvents Have O-H or N-H Bonds And Can Hydrogen-Bond With Themselves. “Aprotic” Solvents Cannot Be Hydrogen Bond Donors There’s a final distinction to be made and this also causes confusion. Some solvents are called “protic” and some are called “aprotic”. What makes ...
Dielectric constantRelaxation timeIntermolecular interactions.The density (ρ), refractive index (n_D), dielectric constant (ε_s) and relaxation time (τ) of binary mixture of allyl bromide with polar protic solvent n-butanol including those of the pure liquids, were measured over the complete ...
Such interpolymer complex formations were examined in several protic and aprotic solvents. The obvious relationship between the complex formation and the dielectric constant of the solvent was eludicated. The effect of hydrophobic interactions ... H Ohno,K Abe,E Tsuchida - 《Die Makromolekulare Chem...
Polar aprotic solvents, like tetrahydrofuran, are better solvents for this reaction than polar protic solvents because polar protic solvents will be solvated by the solvent hydrogen bonding to the nucleophile and thus hindering it from attacking the carbon with the leaving group. A polar aprotic ...
关键词: solubilities potassium fluoride protic and aprotic polar solvents correlation DOI: 10.1134/S0036024412130134 被引量: 1 年份: 2012 收藏 引用 批量引用 报错 分享 全部来源 免费下载 求助全文 全文购买 Springer (全网免费下载) Springer 国家科技图书文献中心 (权威机构) 掌桥科研 dx.doi.org 查看更多...
the polar protic solvents are those that contain the $ \text{N-H} $ bonds and $ \text{O...
Their main respective advantages are discussed with regard to the solvent and polymer chemical structures and the type of interactions involved in the sorption phenomenon.UNIQUAC-FV is shown to provide the best results for the sorption of aprotic species (ether, ester) in polyurethaneimides, as ...
The mechanism of vibrational frequency fluctuations for the antisymmetric stretching modes of SCNand N3is discussed in terms of the difference between protic and aprotic solvents. 展开 关键词: Experimental/ dissociation fluctuations hydrogen bonds infrared spectra negative ions nitrogen photon echo solvent ...
Synthesis, Crystalline Complex Formation and X-Ray Crystal Structures of Three Inclusion Species have been prepared and shown to act as crystallinehosts for the inclusion of organic solvents involving protic polar, aprotic dipolar and apolar molecules. ... EDWIN,WEBER,KONSTANTINOS,... - 《Journal ...
At a solvent-to-water ratio of 4/1 (v/v) the aprotic solvent acetonitrile gave significantly lower quantities of NVRs compared to the protic solvents methanol and ethanol. Decrease of the solvent-to-water ratio from 4/1 to 1/1 (v/v) led in case of ethanol and acetonitrile to massively...