On thermolysis of the title compound (III), cleavage of the P-C bond in a PMe3 ligand occurs with transformation to a dimethylarylphosphinite ligand in the orthometalated product (IV) (space group P21/n, Z = 8).doi:10.1002/chin.199050278...
Solution structure and ligand exchange in the five-coordinate molecular complexes NiX2(PMe3)3organo‐nickel compoundsNot Availabledoi:10.1002/chin.197651282MEIER, P.MERBACH, A. E.DARTIGUENAVE, M.DARTIGUENAVE, Y.Wiley-BlackwellChemischer Informationsdienst...
A comparative analysis of resulting low-temperature CCD X-ray diffractometry determinations revealed an amazing molecular similarity between the actual shapes of the highly deformed Au4Pd28 architectures and ligand connectivities of 1 within the two dissimilar crystal structures. These results clearly ...
Stoichiometric reactions of 2 with benzaldehyde and cyclohexanone start with dissociation of the trans-to-hydride PMe3 ligand followed by coordination and insertion of carbonyls into the Mo–H bond to form alkoxy derivatives (ArN=)Mo(Cl)(OR)(PMe2)L2 (3: R = OCH2Ph, L2 = 2 PMe3; 5: ...
Heating complex 4 with cis-[Mo(PMe3)4(N2)2] induces a germylidyne ligand transfer from rhenium to molybdenum to afford the germylidyne complex trans-[Cl(PMe3)4MoGeC6H3-2,6-Trip2] (10). All new compounds were fully characterized and their molecular structures studied by X-ray...
Experimental and computational study of metal-ligand cooperation in H-H and C-H bond activation via reversible ligand dearomatization 2010, Organometallics Reduction and C(sp2)-H bond activation of ketones promoted by a cyclopentadienyl-osmium-dihydride-dihydrogen complex 2005, Organometallics ...
Synthesis and ligand substitution reactions of κ4-B,S,S',S''-ruthenaboratranes. A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S',S''-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of th... Mark,R,St-J,... - 《Dalton...
Preparation and ligand properties of bis-thionylimino complexes of the type M(NSO)2(PR3)2. X-ray structure of Pt(NSO)2(PMe3)2 The equilibrium geometries and bond dissociation energies of the complexes L2TM-C2H2 and L2TM-C2H4 (TM = Ni, Pd, Pt) with the monodentate ligands L-2 = (PH...
With {Rh(μ-Cl)(cod)}2, the product contains an Re2Rh cluster capped by the CH(PPh2)2 ligand. The X-ray structures of 4, 6 and 8–11 are reported.Access through your organization Check access to the full text by signing in through your organization. Access through your organization...
Compound 1 is the first reported bismuth-phosphine complex and comprises a polymeric anion, the monomeric unit of which contains a planar Bi2Br6 core, each bismuth being further bonded to a PMe3 ligand and an additional bromide such that the bismuth resides in an octahedral coordination ...