大概意思就是,形容芳香分子面对面的堆积状态,生物上用来形容DNA碱基配对
Targeted disruption of pi–pi stacking in Malaysian banana lectin reduces mitogenicity while preserving antiviral activityLECTINSANTIVIRAL agentsPROTEIN foldingAMINO acidsAROMATIC compoundsLectins, carbohydrate-binding proteins, have been regarded as potential antiviral agents, as some can bind glycans on viral...
请问一下大牛,pi-pi stacking 到底是个什么作用力?是否有利于高分子链相互作用呢?
which, through disruption of pi–pi stacking in the third Greek key of BanLec, appears to diminish the capacity of H84T BanLec (H84T) to interact with multiple glycan molecules, which is required for mitogenicity. However, importantly, H84T retains the potent antiviral...
审稿人返回的邮件让我解释,不同碳材料之间是仅仅Pi-Pi stacking还是有化学作用,但是又不知道Pi-Pi ...
Anyone know anything about the kinetics of π-π stacking in crystals? I have a new cocrystal which I've done some UNI potentials analysis looking at the growth rate of faces and found that the fastest faces grow primarily by pi stacking. I know that the strength of these intermolecular bon...
The pi-stacking of oxidized thiophene oligomers is investigated using ab-initio quantum chemistry methods. Dimers of singly-charged oligothiophenes are found to be unstable in the gas phase, but can be stabilized as bound dications in the singlet state by a polarizable solvent such as acetonitrile...
[reaction: see text] The effects of pi-stacking on the stability of multiply hydrogen-bonded systems are investigated using hybrid DFT calculations on pi-stacked quadruply H-bonded dimers of ureidopyrimidinone in its different tautomeric forms. Both the strengths of the hydrogen bonds and the relati...
通过独立梯度模型(IGM)考察分子间弱相互作用 http://sobereva.com/407 使用Multiwfn图形化研究弱相互作用...
Cation-cation pi-pi stacking dimers can be formed in a dielectric solvent due to significant screening of the charge-charge repulsion forces. However, such species in small clusters have not been reported. Calculations reported in this work suggest that cation-cation pi-pi stacking structures can ...