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Phthalimide-N-oxyl (PINO) radical, a powerful catalytic agent: Its generation and versatility towards various organic substrates. Catalysis Reviews, 51, 218-292.Phthalimide-N-oxyl (PINO) Radical, a Powerful Catalytic Agent: Its Generation and Versatility Towards Various Organic Substrates[J] . ...
The reactions of the phthalimide N-oxyl (PINO) radical with several hydrocarbons having different C-H bond dissociation energies (BDEs) were investigated in HOAc at 25 °C. The slope of the Evans-Polanyi plot is 0.38, which indicates that the reactions are mildly exothermic or almost thermoneutr...
Kinetic study of the phthalimide N-oxyl (PINO) radical in acetic acid. Hydrogen abstraction from C-H bonds and evaluation of O-H bond dissociation energy of N-hydroxyphthalimide. Koshino, Nobuyoshi,Cai, Yang,Espenson, James H. Journal of Physics . 2003...
Free radicalEPRCatalysisIrradiation of N-triphenylmethyloxy- or N-diphenylmethyloxy phthalimide is reported to result in the formation of phthalimide N-oxyl radical (PINO), which is able to initiate and propagate oxidative radical chain reactions of hydrocarbons....
phthalimide N-oxyl radicaldensity functional theoryelectron transfer reactionsThe usefulness of global descriptors based on the density functional theory framework has been discussed in the context of electron transfer reactions. A simple relationship between the vertical electronic energy associated to the ...
Phthalimide-N-oxyl (PINO) and benzotriazole-N-oxyl (BTNO) radicalsRadical additionPhilicityVinyl compoundsIn this paper, we report the comparative investigation of reactivity of phthalimide-N-oxyl (PINO) and benzotriazole-N-oxyl (BTNO) radicals toward double bonds of vinyl compounds. The rate ...
N-hydroxyphthalimideoxidationsulfideselectron transferradicalThe oxidation of a series of alkyl aryl sulfides promoted by the phthalimide N -oxyl radical (PINO) has been investigated by kinetic and product analysis. Sulfoxides are formed as major reaction products in the oxidation of thioanisoles and ...
A kinetic study of the electron-transfer reaction of the phthalimide-N-oxyl radical (PINO) with ferrocenes. Baciocchi, Enrico,Bietti, Massimo,Di Fusco, Massimo,Lanzalunga, Osvaldo. Journal of Organic Chemistry . 2007Enrico Baciocchi,Massimo Bietti,Massimo Di Fusco. A Kinetic Study of the ...
Kinetics Electron-Transfer Rxn of the Phthalimide-N-oxyl Radical PINO w FerroceneBaciocchi, EBietti, MDi Fusco, MLanzalunga, O